Abstract
The dependence of the reaction rate of cyclopentanol with phenyl isocyanate on the concentration of monomeric alcohol [1] in toluene, di-n-butyl ether and acetonitrile suggests a reaction scheme involving various complexes.
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A.-C. Draye, J.-J. Tondeur, G. Vandendughen:Spectrochim. Acta Part A,52, 1757 (1966).
Yu.Ya. Borovikov, Yu.P. Egorov, O.V. Vishnevskii, V.I. Gorbatenko:Zh. Obshch. Khim.,43, 2484 (1973).
J.W. Baker, J. Gaunt:J. Chem. Soc., 27 (1949).
S. Ephraim, A.E. Woodward, R.B. Mesrobian:J. Am. Chem. Soc.,80, 1326 (1958).
R.P. Tiger, L.S. Bekhli, S.P. Bondarenko, S.G. Entelis:Zh. Org. Khim.,9, 1563 (1973).
H. Hernandez Suarez, M.G. Makarov, A.B. Kudryavtsev, V.I. Ermakov:Kinet. Katal.,23, 213 (1982).
M.-C. Chang, S.-A. Chen:J. Polym. Sci., Part A: Polym. Chem.,25, 2453 (1987).
R.P. Tiger, S.G. Entelis:Kinet. Katal.,6, 544 (1965).
R.P. Tiger, L.S. Bekhli, S.G. Entelis:Kinet. Katal.,15, 586 (1972).
S.G. Entelis, P.A. Berlin, R.P. Tiger, S.P. Bondarenko:4th International Symposium on Homogeneous Catalysis, Leningrad, 1985.
V. Gutmann:Electrochim. Acta,21, 661 (1976).
K. Schwetlick, R. Noack:J. Chem. Soc. Perkin Trans. 2, 395 (1995).
K.A. Connors:Chemical Kinetics—The Study of Reaction Rates in Solution, p.440. VCH publishers, New York, Weinheim, Cambridge, 1990.
C. Laurence: Université de Nantes, private communication.
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Draye, A.C., Tarasov, D.N. & Tondeur, J.J. Solvent-assisted alcohol-isocyanate kinetics. React Kinet Catal Lett 66, 199–204 (1999). https://doi.org/10.1007/BF02475790
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DOI: https://doi.org/10.1007/BF02475790