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Catalytic hydrodechlorination of chlorobenzene in liquide phase

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Abstract

Catalytic hydrodechlorination of chlorobenzene (CB) was carried out in the liquid phase in a mixture of methanol/water (MeOH/H2O) at 30°C and 2kg/cm2 pressure. The reaction orders with respect to CB and H2 pressure were one and zero, respectively. Addition of NH4OH in the reaction produces a decrease in the activity (TOF). Solvent effect shows the following order of activity: H2O>MeOH/H2O>EtOH/H2O>MeOH.

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Authors and Affiliations

  1. Departmento de Desarrollo de productos Químicos, Instituto Mexicano del Petróleo, Eje Central Norte Lázaro Cárdenas 152, A.P. 14-805, 07730, México, D.F.

    José Luis Benítez

  2. Departamento de Química, Universidad Autónoma Metropolitana-Iztapalapa, P.O. Box 55-534, 09340 D.F., México

    Gloria Del Angel

Authors
  1. José Luis Benítez
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  2. Gloria Del Angel
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Benítez, J.L., Angel, G.D. Catalytic hydrodechlorination of chlorobenzene in liquide phase. React Kinet Catal Lett 66, 13–18 (1999). https://doi.org/10.1007/BF02475735

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  • DOI: https://doi.org/10.1007/BF02475735

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