Skip to main content
SpringerLink
Log in

A kinetic approach to homogeneous Ziegler type polymerization. Steady state

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

In this paper we present a kinetic approach to the analysis of steady-state homogeneous Ziegler-Natta polymerization activity data. The influence of the number of monomeric species that are coordinated to the active site on the apparent rate law is discussed and the equations are fitted to the experimental results.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Z. Yu, M. Marques, J.C. Flores, M.D. Rausch, J.C.W. Chien: submitted to publication.

  2. M. Ystenes:J. Catal.,129, 383 (1991).

    Article  CAS  Google Scholar 

  3. V. Busico, R. Cipullo:J. Am. Chem. Soc.,116 9329 (1994); (b) V. Busico, R. Cipullo, J.C. Chadwick, J.F. Modder, O. Sudmeijer:Macromolecules,27, 7538 (1994).

    Article  CAS  Google Scholar 

  4. L. Resconi, A. Fait, F. Piemontesi, M. Colonnesi, H. Rychlicki, R. Zeigler:Macromolecules,28, 6667 (1995).

    Article  CAS  Google Scholar 

  5. S. Jungling, R. Mulhaupt, U. Stehling, H.-H. Brintzinger, D. Fischer, F. Langhauser:Macromol. Symp.,97, 205 (1995).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Centro de Química Estrutural, Instituto Superior Técnico, Av. Rovisco Pais 1, 1096, Lisboa Codex, Portugal

    Maria Merces Marques & A. R. Dias

  2. Centro de Engenharia Biológica e Química, Dept. Eng. Química, Instituto Superior Técnico, Av. Rovisco Pais 1, 1096, Lisboa Codex, Portugal

    C. Costa, F. Lemos & F. Ramôa Ribeiro

Authors
  1. Maria Merces Marques
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Costa
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Lemos
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. Ramôa Ribeiro
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. A. R. Dias
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Marques, M.M., Costa, C., Lemos, F. et al. A kinetic approach to homogeneous Ziegler type polymerization. Steady state. React Kinet Catal Lett 62, 9–15 (1997). https://doi.org/10.1007/BF02475707

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02475707

Keywords

Search

Navigation