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Reaction Kinetics and Catalysis Letters

, Volume 62, Issue 1, pp 9–15 | Cite as

A kinetic approach to homogeneous Ziegler type polymerization. Steady state

  • Maria Merces Marques
  • C. Costa
  • F. Lemos
  • F. Ramôa Ribeiro
  • A. R. Dias
Article

Abstract

In this paper we present a kinetic approach to the analysis of steady-state homogeneous Ziegler-Natta polymerization activity data. The influence of the number of monomeric species that are coordinated to the active site on the apparent rate law is discussed and the equations are fitted to the experimental results.

Keywords

Olefin polymerization Ziegler-Natta catalysis 

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Copyright information

© Akadémiai Kiadó 1997

Authors and Affiliations

  • Maria Merces Marques
    • 1
  • C. Costa
    • 2
  • F. Lemos
    • 2
  • F. Ramôa Ribeiro
    • 2
  • A. R. Dias
    • 1
  1. 1.Centro de Química EstruturalInstituto Superior TécnicoLisboa CodexPortugal
  2. 2.Centro de Engenharia Biológica e Química, Dept. Eng. QuímicaInstituto Superior TécnicoLisboa CodexPortugal

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