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Oxidative dehydrogenation of ethane with carbon dioxide over sulfated zirconia supported metal oxides catalysts

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Abstract

Several metal oxides supported on sulfated zirconia catalysts were tested for the oxidative dehydrogenation of ethane into ethylene by carbon dioxide. It is found that the catalytic behavior of supported oxide catalysts differ depending on the nature of metal oxides. Chromium oxide-sulfated zirconia exhibits the highest ethane conversion and medium level of ethylene selectivity, producing 38% ethylene yield at 50% ethane conversion at 650°C.

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Authors and Affiliations

  1. Department of Surface Chemistry, National Institute of Materials and Chemical Research, 305, Tsukuba, Ibaraki, Japan

    Shaobin Wang, Kazuhisa Murata, Takashi Hayakawa, Satoshi Hamakawa & Kunio Suzuki

Authors
  1. Shaobin Wang
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  2. Kazuhisa Murata
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  3. Takashi Hayakawa
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  4. Satoshi Hamakawa
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  5. Kunio Suzuki
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Wang, S., Murata, K., Hayakawa, T. et al. Oxidative dehydrogenation of ethane with carbon dioxide over sulfated zirconia supported metal oxides catalysts. React Kinet Catal Lett 68, 265–270 (1999). https://doi.org/10.1007/BF02475511

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  • DOI: https://doi.org/10.1007/BF02475511

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