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Reaction Kinetics and Catalysis Letters

, Volume 68, Issue 2, pp 265–270 | Cite as

Oxidative dehydrogenation of ethane with carbon dioxide over sulfated zirconia supported metal oxides catalysts

  • Shaobin Wang
  • Kazuhisa Murata
  • Takashi Hayakawa
  • Satoshi Hamakawa
  • Kunio Suzuki
Article

Abstract

Several metal oxides supported on sulfated zirconia catalysts were tested for the oxidative dehydrogenation of ethane into ethylene by carbon dioxide. It is found that the catalytic behavior of supported oxide catalysts differ depending on the nature of metal oxides. Chromium oxide-sulfated zirconia exhibits the highest ethane conversion and medium level of ethylene selectivity, producing 38% ethylene yield at 50% ethane conversion at 650°C.

Keywords

Dehydrogenation ethylene sulfated zirconia carbon dioxide metal oxides 

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Copyright information

© Akadémiai Kiadó 1999

Authors and Affiliations

  • Shaobin Wang
    • 1
  • Kazuhisa Murata
    • 1
  • Takashi Hayakawa
    • 1
  • Satoshi Hamakawa
    • 1
  • Kunio Suzuki
    • 1
  1. 1.Department of Surface ChemistryNational Institute of Materials and Chemical ResearchTsukubaJapan

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