Abstract
The presence of added hydrogen does not significantly alter the relative conversion of methylcyclohexane andn-octane. The results for conversion at a total pressure of 0.1 mPa are consistent with a mechanism where chemisorption is irreversible and rate limiting even where the hydrogen partial pressure is 0.094 mPa.
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B.L. Moldvasky, H.D. Kamisher:Compt. rend acad. sci. U.R.S.S.,1, 355 (1936).
V.I. Karshev, M.G. Severyanova, A.N. Siova:Khimiya Tverdogo Topliva (Chem. Solid Fuel),8, 559 (1936).
B.A. Kazanski, A.F. Plate:Ber.,69, 1862 (1936).
A.V. Grosse, J.C. Morrell, W.J. Mattox:Ind. Eng. Chem.,32, 528 (1940).
A.V. Grosse, J.C. Morrell: U. S. Patents 2,124,566, 2,124,567; 2,124,583; 2,124,584; 2,124,585; and 2,124,586; July, 1938.
J. Turkevich: in “Heterogeneous Catalysis. Selected American Histories,” (B.H. Davis, W.P. Hettinger, Jr., Eds.),ACS Symp. Series,222, 463 (1982).
S. Goldwasser, H.S. Taylor,J. Am. Chem. Soc.,61, 1766 (1939).
S. Groueff:Manhattan Project: The Untold Story of the Making of the Atomic Bomb, pp. 263–264. Little, Brown, Company, Boston, 1967.
B.H. Davis.Appl. Catal.,115, N27 (1994).
E.F.G. Herington, E. Rideal:Proc. Royal Soc. (London),144, 434 (1945).
E.F.G. Herington, E. Rideal:Proc. Royal Soc. (London),144, 447 (1945).
J.J. Mitchell:J. Am. Chem. Soc.,80, 5848 (1958).
H. Pines, C.T. Chen:2nd Int. Congr. Catal., 367 (1961).
H. Pines, C.T. Chen:J. Org. Chem.,26, 1057 (1961).
B.H. Davis:Selectivity in Catalysis, (M.E. Davis, S.L. Suib, eds.),ACS Symp. Series,517, 109 (1993).
O.V. Bragin, Z. Karpinski, K. Matusek, Z. Paál, P. Tétényi:J. Catal.,56, 219 (1979).
Z. Hiavathy, P. Tétényi, Z. Paál:J. Chem. Soc. Farad. Trans.,88, 2059 (1992).
Z. Paál, P. Tétényi:Appl. Catal.,1, 9 (1981).
Z. Paál, P. Tétényi:Acta Chim. Acad. Sci. Hung.,54, 175 (1967).
Z. Paál, G. Székely, P. Tétényi:J. Catal.,58, 108 (1979).
Z. Paál, P. Tétényi:Kémiai Közlem.,28, 13 (1967).
Z. Paál, P. Tétényl:Nature,67, 234 (1977).
P. Tétényi, Z. Paál:Acta Chim. Acad. Sci. Hung.,119, 83 (1985).
H. Zimmer, Z. Paál, P. Tétényi:Acta Chim. Acad. Sci. Hung.,111, 513 (1982).
P. Tétényi:Catal. Today,17, 439 (1993).
M. Dobrovolszky, Z. Paál, P. Tétényi:React. Kinet. Catal. Lett.,51, 101 (1993).
Z. Paál, P. Tétényi:J. Catal.,30, 350 (1973).
H. Zimmer, M. Dobrovolszky, P. Tétényi, Z. Paál:J. Phys. Chem.,90, 4758 (1986).
Z. Paál, H. Zimmer, P. Tétényi:J. Mol. Catal.,25, 99 (1984).
H. Zimmer, P. Tétényi, Z. Paál:J. Chem. Soc. Farad. Trans.,78, 3573 (1982).
H. Zimmer, M. Dobrovolszky, P. Tétényi, Z. Paál:J. Phys. Chem.,90, 4758 (1986).
B.H. Davis:J. Catal.,23, 365 (1971).
B. Shi, B.H. Davis:J. Catal.,147, 38 (1994).
B. Shi, B.H. DavisJ. Catal.,157, 626 (1995).
B. Shi, B.H. Davis:11th Int. Congr. Catal., (J.W. Hightower, W.N. Delgass, E. Iglesia, A.T. Bell, eds.), (Studies in Surf. Sci. Catal.),101 (B), 1145. Elsevier, Amsterdam (1996).
B. Shi, B.H. Davis:J. Catal.,162, 134 (1966).
B. Shi, B.H. Davis:J. Catal.,168, 129 (1997).
Y. Wang, B. Shi, R.D. Guthrie, B.H. Davis:J. Catal.,170, 89 (1997).
Y. Wang, B.H. Davis: unpublished results.
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Dedicated to Professor Pál Tétényi on the occasion of his 70th birthday
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Wang, Y., Guthrie, R.D. & Davis, B.H. Competitive conversion of methylcyclohexane andn-octane. Variation of hydrogen partial pressure. React Kinet Catal Lett 68, 145–151 (1999). https://doi.org/10.1007/BF02475496
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DOI: https://doi.org/10.1007/BF02475496