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Synergic effect of palladium-based bimetallic catalysts for the hydrogenation of nitroaromatics

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Abstract

Bimetallic catalysts, PdCl2-MXn and PdCl2(PhCN)2-Mxn (MXn=FeCl3, Fe(acac)3, Co(OAc)2, CoCl2, Co(acac)2, NiCl2, Ni(OAc)2, RuCl3, Cu(OAc)2, CuCl2), exhibit remarkable synergic effect which can obviously increase the activity of the monometallic Pd catalyst for the hydrogenation of nitroaromatics, whereas MXn alone is not catalytically active under the same reaction conditions.

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Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, P.O. Box 110, 116023, Dalian, P. R. China

    Bo-Shun Wan, Shi-Jian Liao, Yun Xu & Dao-Rong Yu

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  1. Bo-Shun Wan
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  2. Shi-Jian Liao
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  3. Yun Xu
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  4. Dao-Rong Yu
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Wan, BS., Liao, SJ., Xu, Y. et al. Synergic effect of palladium-based bimetallic catalysts for the hydrogenation of nitroaromatics. React Kinet Catal Lett 63, 397–401 (1998). https://doi.org/10.1007/BF02475418

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  • DOI: https://doi.org/10.1007/BF02475418

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