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Manganese(II) β-diketonate catalyzed oxidation of cyclohexane bytert-butyl hydroperoxide

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Abstract

Oxidation of cyclohexane bytert-butyl hydroperoxide was carried out in acetonitrile solution at room temperature in the presence of manganese(II) β-diketonate complexes, Mn(acac)2, Mn(acac)2.2H2O, Mn(ba)2.H2O, Mn(dbm)2 and Mn(dbm)2.2H2O (where acacH=acetylacetone, baH=benzoylacetone and dbmH=dibenzoyl-methane). Cyclohexanol and cyclohexanone were obtained as the products. Oxidation ofcis-cyclooctene gave the corresponding epoxide together with two minor byproducts in the presence of Mn(acac)2.2H2O and Mn(dbm)2.2H2O. A mechanistic pathway predominantly involving autoxidation is proposed.

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Authors and Affiliations

  1. Research Centre, Indian Petrochemicals Corporation Limited, 391 346, Vadodara, India

    Gopal L. Tembe, Pralhad A. Ganeshpure & Sheo Satish

Authors
  1. Gopal L. Tembe
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  2. Pralhad A. Ganeshpure
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  3. Sheo Satish
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IPCL communication No. 322

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Tembe, G.L., Ganeshpure, P.A. & Satish, S. Manganese(II) β-diketonate catalyzed oxidation of cyclohexane bytert-butyl hydroperoxide. React Kinet Catal Lett 63, 385–389 (1998). https://doi.org/10.1007/BF02475416

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  • DOI: https://doi.org/10.1007/BF02475416

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