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Ammoxidation of toluene on vanadyl polyphosphates-VO(PO3)2, 2. Catalytic properties

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Abstract

Crystalline and amorphous vanadyl polyphosphates (VO(PO3)2) with a P/V ratio=2 were used as catalysts in the ammoxidation of toluene. The crystalline specimens exhibit a rather low activity compared with the amorphous solid. The benzonitrile selectivities always reached nearly 90%. Noticeable benzaldehyde amounts were detected that could be due to an inadequate ammonia activation on the solid surface.

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Author notes

  1. Fouzia K. Hannour

    Present address: Department of Chemical Engineering, University of Technology of Compiégne, France

Authors and Affiliations

  1. Institut für Angewandte Chemie Berlin-Adlershof e.V., Rudower Chaussee 5, D-12489, Berlin, Germany

    Andreas Martin, Fouzia K. Hannour, Angelika Brückner & Bernhard Lücke

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  1. Andreas Martin
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  2. Fouzia K. Hannour
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  3. Angelika Brückner
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  4. Bernhard Lücke
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Martin, A., Hannour, F.K., Brückner, A. et al. Ammoxidation of toluene on vanadyl polyphosphates-VO(PO3)2, 2. Catalytic properties. React Kinet Catal Lett 63, 245–251 (1998). https://doi.org/10.1007/BF02475395

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  • DOI: https://doi.org/10.1007/BF02475395

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