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A theoretical study of the rotational distribution of no resulting from dissociation of HNO

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Abstract

Nascent NO (X2ΠΩ=1/2, 3/2, v=0) rotational distributions following the unimolecular dissociation of HNO at 5 and 300 K have been calculated at excess energies from 5 to 500 cm−1, using the statistical adiabatic channel model on anab initio potential energy surface. The influence of the tunneling effect through the adiabatic channel barriers on the average rotational energies is investigated.

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Authors and Affiliations

  1. Instituto de Investigaciones Fisicoquímicas Teóricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, C.C. 16, Suc. 4, (1900), La Plata, Argentina

    C. J. Cobos

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  1. C. J. Cobos
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Cobos, C.J. A theoretical study of the rotational distribution of no resulting from dissociation of HNO. React Kinet Catal Lett 64, 199–205 (1998). https://doi.org/10.1007/BF02475389

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  • DOI: https://doi.org/10.1007/BF02475389

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