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Isomerization of 3,3-dimethyl-1-butene over aluminum and chromium orthophosphates

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Abstract

The skeletal isomerization of 3,3-dimethyl-1-butene over AlPO4 (Al/P=1), CrPO4 (Cr/P=1), and CrPO4−AlPO4 (CrAlP, 5–10 wt.% AlPO4) catalysts is a first order reaction. Catalytic performance is affected by the precipitation agent. CrPO4 catalysts obtained in propylene oxide-aqueous ammonia showed the highest activity. Moreover, the incorporation of AlPO4 to CrPO4 developed CrAlP catalysts that exhibited increased activity, irrespective of the precipitation method, as compared with both AlPO4 and CrPO4 catalysts. Besides, CrAlP catalysts prepared in propylene oxide-aqueous ammonia were the more active ones.

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References

  1. H. Pines:The chemistry of Catalytic Hydrocarbon Conversions, Academic Press, New York 1981.

    Google Scholar 

  2. H. Pines:J. Catal.,78, 1 (1982).

    Article  CAS  Google Scholar 

  3. C. S. John, C. Kemball, R. A. Rajadhyaksha:J. Catal.,57, 264 (1979).

    Article  CAS  Google Scholar 

  4. E. A. Irvine, C. S. John, C. Kemball, A. J. Pearman, M. A. Day, R. J. Sampson:J. Catal.,61, 326 (1980).

    Article  CAS  Google Scholar 

  5. C. Kemball, H.F. Leach, B. Skrundic, K.C. Taylor:J. Catal.,27, 416 (1972).

    Article  CAS  Google Scholar 

  6. A. Corado, A. Kiss, H. Knozinger, H.D. Muller:J. Catal.,37, 68 (1975).

    Article  CAS  Google Scholar 

  7. M. S. Scurrell, B. W. Moller, C. Kemball:J. Chem. Soc., Faraday Trans. I,72, 2512 (1976).

    Article  CAS  Google Scholar 

  8. G. Gáti, I. Halász, G. Resofszki:Appl. Catal.,9, 213 (1984).

    Article  Google Scholar 

  9. B.I. Brookes, R. Bird, C. Kemball, H.F. Leach:J. Chem. Soc., Faraday Trans. I,85, 2173 (1989).

    Article  CAS  Google Scholar 

  10. D. Martin, D. Duprez:J. Mol. Catal. A,118, 113 (1997).

    Article  CAS  Google Scholar 

  11. B. Gallace, J.B. Moffat:J. Catal.,76, 182 (1982).

    Article  CAS  Google Scholar 

  12. A. Florentino, P. Cartraud, P. Magnoux, M. Guisnet:Appl. Catal A,89, 142 (1992).

    Google Scholar 

  13. M. Guisnet:Acc. Chem. Res.,23, 392 (1990).

    Article  CAS  Google Scholar 

  14. J.M. Campelo, A. Garcia, J.F. Herencia, D. Luna, J.M. Marinas, A.A. Romero:J. Catal.,151, 307 (1995), and references therein.

    Article  CAS  Google Scholar 

  15. F.M. Bautista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, M.R. Urbano:J. Mater. Chem.,3, 975 (1993).

    Article  CAS  Google Scholar 

  16. F.M. Bautista, J.M. Campelo, A. Garcia, D. Luna, J.M. Marinas, M.R. Urbano:J. Mater. Chem.,4, 311 (1994).

    Article  CAS  Google Scholar 

  17. D. Bassett, H.W. Habgood:J.Phys. Chem.,64, 769 (1960).

    CAS  Google Scholar 

  18. A.J. van Roosmalen, J.C. Mol:J. Chem. Soc. Chem. Commun., 804 (1980).

  19. A.J. van Roosmalen, M.C.G. Hartmann, J. C. Mol:J. Catal.,66, 112 (1980).

    Article  Google Scholar 

  20. A.N. Ko, B.W. Wojciechowski:Prog. React. Kinet.,12, 201 (1983).

    Google Scholar 

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Authors and Affiliations

  1. Department of Organic Chemistry, Sciences Faculty, Cordoba University, Avda. S. Alberto Magno, s/n0, E-14004, Cordoba, España

    F. M. Bautista, J. M. Campelo, A. Garcia, D. Luna, J. M. Marinas, A. A. Romero & M. R. Urbano

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  1. F. M. Bautista
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  2. J. M. Campelo
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  3. A. Garcia
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  4. D. Luna
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  5. J. M. Marinas
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  6. A. A. Romero
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  7. M. R. Urbano
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Bautista, F.M., Campelo, J.M., Garcia, A. et al. Isomerization of 3,3-dimethyl-1-butene over aluminum and chromium orthophosphates. React Kinet Catal Lett 64, 41–48 (1998). https://doi.org/10.1007/BF02475368

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  • DOI: https://doi.org/10.1007/BF02475368

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