The detailed balance principle in matrix kinetics
The method to derive the rate matrix K of a chemical reaction in a direct and straightforward way is here completed with the introduction of a new rule due to the application of the detailed balance principle. This principle let us discover a further characteristic of the rate matrices for cyclic reactions, a characteristic that can be used both to check the validity of the rate matrix and to improve the mechanical method used to derive the structure of these matrices in a straightforward way.
KeywordsDetailed balance structure of rate matrices
- 1.M.N. Berberan-Santos, J.M.G. Martinho:J. Chem. Educ.,67, 375 (1990).Google Scholar
- 7.R.A. Alberty, R.J. Silbey:Physical Chemistry, Wiley, New York 1992.Google Scholar
- 8.W.J. Moore:Physical Chemistry, Longman, London 1978.Google Scholar
- 9.S.J. Formosinho:Fundamentos de Cinetica Quimica, Gulbenkian, Lisboa 1982.Google Scholar