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The detailed balance principle in matrix kinetics

  • Lionello Pogliani
Article

Abstract

The method to derive the rate matrix K of a chemical reaction in a direct and straightforward way is here completed with the introduction of a new rule due to the application of the detailed balance principle. This principle let us discover a further characteristic of the rate matrices for cyclic reactions, a characteristic that can be used both to check the validity of the rate matrix and to improve the mechanical method used to derive the structure of these matrices in a straightforward way.

Keywords

Detailed balance structure of rate matrices 

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Copyright information

© Akadémiai Kiadó 1998

Authors and Affiliations

  • Lionello Pogliani
    • 1
  1. 1.Dipartimento di ChimicaUniversitá della CalabriaRende (CS)Italy

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