Reaction Kinetics and Catalysis Letters

, Volume 65, Issue 2, pp 311–314 | Cite as

Quantitative description of the effect of solvent on kinetics of benzophenone oxide decay

  • A. M. Nazarov
  • E. M. Chainikova
  • S. L. Khursan
  • I. A. Kalinichenko
  • R. L. Safiullin
  • V. D. Komissarov
Article

Abstract

The effect of solvent on rate constants of benzophenone oxide decay was investigated by flash photolysis. A quantitative description of this dependence in the terms of the Koppel-Palm equation suggests that all types of the solvation (non-specific electrostatic and polarizational, specific electrophilic and nucleophilic) strongly affect the reactivity of benzophenone oxide. Besides, strengthening of any effect leads to a decrease of the observed rate constant.

Keywords

Carbonyl oxides kinetics flash photolysis correlation equations 

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Copyright information

© Akadémiai Kiadó 1998

Authors and Affiliations

  • A. M. Nazarov
    • 1
  • E. M. Chainikova
    • 1
  • S. L. Khursan
    • 2
  • I. A. Kalinichenko
    • 1
  • R. L. Safiullin
    • 1
  • V. D. Komissarov
    • 2
  1. 1.Institute of Organic ChemistryUfa Research Center of the Russian Academy of SciencesUfaRussia
  2. 2.Bashkir State UniversityUfaRussia

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