Quantitative description of the effect of solvent on kinetics of benzophenone oxide decay
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The effect of solvent on rate constants of benzophenone oxide decay was investigated by flash photolysis. A quantitative description of this dependence in the terms of the Koppel-Palm equation suggests that all types of the solvation (non-specific electrostatic and polarizational, specific electrophilic and nucleophilic) strongly affect the reactivity of benzophenone oxide. Besides, strengthening of any effect leads to a decrease of the observed rate constant.
KeywordsCarbonyl oxides kinetics flash photolysis correlation equations
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