Summary
An oxalic acid-α-hydroxyisobutyric acid eluent has been used for the separation and determination of rare-earth elements by high-performance ion-exchange chromatography. Fifteen rare-earth elements were separated within less than 25 min on a 150×4.6 mm i.d. column packed with 5-μm sulfonic acid-bonded silica particles by elution with a combined gradient of 0.60–9.0 mM oxalic acid and 19.0–5.0 mM α-hydroxyisobutyric acid at pH 4.6. Detection and quantitation of the separated rare-earth elements was accomplished by visible-absorbance measurements at 600 nm after postcolumn reaction with arsenazo I. The gradient of the two complexing agents was optimized to enable the separation of yttrium(III) without interference from other elements, especially dysprosium(III) and terbium(III). Mass detection limits of the elements were in the range of 2–4 ng. Finally, the chromatographic system was applied to the quantitative analysis of rare-earth elements in monazite and xenotime.
Similar content being viewed by others
References
P. Henderson (Editor), Rare Earth Element Geochemistry, Elsevier, Amsterdam, 1984.
K. C. Condie, G. P. Bowhry, P. Allen, Contrib. Mineral. Petrol.92, 93 (1986).
K. E. Jarvis, I. Jarvis, Geostand. Newsl.12, 1 (1988).
C. T. Kantipuli, A. D. Westland, Talanta35, 1 (1988).
M. Kumar, Analyst119, 2013 (1994).
D. H. Sisson, V. A. Mode, D. O. Cambell, J. Chromatogr.66, 129 (1972).
S. Elchuk, R. M. Cassidy, Anal. Chem.51, 1434 (1979).
K. Yoshida, H. Haraguchi, Anal. Chem.56, 2580 (1984).
G. J. Sevenich, J. S. Fritz, Anal. Chem.55, 12 (1983).
C. Tong, Z. L. Shan, P. L. Zhu, Chromatographia27, 317 (1989).
W. Wang, Y. Chen, M. Wu, Analyst109, 281 (1984).
K. Kawabata, Y. Kishi, O. Kawaguchi, Y. Watanabe, Y. Inoue, Anal. Chem.63, 2137 (1991).
R. Saraswati, J. Liq. Chromatogr.16, 4095 (1993).
L. E. Vera-Avila, E. Camacho, J. Liq. Chromatogr.15, 835 (1992).
K. Takeda, M. Akiyama, F. Kawakami, M. Sasaki, Bull. Chem. Soc. Jpn59, 2225 (1986).
G. Bonn, S. Reiffenstuhl, P. Jandik, J. Chromatogr.499, 669 (1990).
Y. Inoue, H. Kumagai, Y. Shimomura, T. Yokoyama, T. M. Suzuki, Anal. Chem.68, 1517 (1996).
R. M. Cassidy, F. C. Miller, C. H. Knight, J. C. Roddeck, R. W. Sullivan, Anal. Chem.58, 1389 (1986).
N. M. P. Moraes, H. M. Shihomatsu, J. Chromatogr. A679, 387 (1994).
E. A. Jones, H. S. Sezuidenhout, J. F. V. Staden, J. Chromatogr.537, 277 (1991).
R. Kuroda, T. Wada, Y. Kokubo, K. Oguma, Talanta40 (2), 237 (1993).
C. A. Lucy, L. Gureli, S. Elchuk, Anal. Chem.65, 3320 (1993).
P. Dufek, M. Vobecky, J. Holik, J. Valosek, J. Chromatogr.435, 249 (1988).
R. Kuroda, M. Adachi, K. Oguma, Y. Sato, Chromatographia30, 263 (1990).
E. A. Jones, H. S. Sezuidenhout, J. F. V. Staden, J. Chromatogr.537, 277 (1991).
R. Kuroda, T. Wada, G. Kishimoto, K. Oguma, Chromatographia32, 65 (1991).
J. E. Huheey, Inorganic Chemistry: Principles of Structure and Reactivity, 2nd edition, Harper and Row, London, 1978, pp 692–3.
J. Weiß, Ionenchromatographie, VCH, Weinheim, 1991, p. 199.
P. R. Haddad, R. C. Foley, J. Chromatogr.500, 301 (1990).
A. V. Stepanov, Zh. Neorgan. Khim.16, 2981 (1971).
H. Deelstra, F. Verbeek, Anal. Chim. Acta31, 251 (1964).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Nuryono, Huber, C.G. & Kleboth, K. Ion-exchange chromatography with an oxalic acid-α-hydroxyisobutyric acid eluent for the separation and quantitation of rare-earth elements in monazite and xenotime. Chromatographia 48, 407–414 (1998). https://doi.org/10.1007/BF02467712
Received:
Revised:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/BF02467712