Summary
Capillary zone electrophoresis method has been developed for the separation (and determination) of monoand dimaltosyl-β-cyclodextrins using indirect UV absorbance detection. The separation is based on inclusion complex formation with benzoate ion which is used as background electrolyte and absorbance provider simultaneously. Good resolution of cyclodextrin mixtures can be achieved optimizing the pH and the benzoic acid concentration in the background electrolyte. Capillary zone electrophoresis method has also been developed for the determination of formation constants of inclusion complexes.
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References
M. L. Bender, M. Komiyama, Cyclodextrin Chemistry, Springer, New York, 1978.
J. Szejtli, Cyclodextrins and Their Inclusion Complexes, Akadénliai Kiadó, Budapest, 1982.
J. Szejtli, Cycldextrin Technology, Kluwer Acad. Publ., Dordrecht 1988.
D. Duchene (Editor), New Trends in Cyclodextrins and Derivatives, Edition de Santé, Paris, 1991.
J. Szejtli, T. Osa (Editors), Cyclodextrins, in J.-M. Lehn, J.L. Atwood, J.E.D. Davies, F. Vögtle (Editors), Comprehensive Supramolecular Chemistry, Vol. 3, Pergamon, Oxford-New York-Tokyo, 1996.
S. Li, W. G. Purdy, Chem. Rev.92, 1457 (1992).
H. Nishi, S. Terabe, J. Chromatogr. A675, 245 (1994).
M. Makela, T. Korpela, J. Puisto, S. Laakso, J. Agric. Food Chem36, 83 (1988).
T. Takeuchi, M. Murayama, D. Ishii, J. High Res. Chromatogr.13, 69 (1990).
J. Haginaka, Y. Nishimura, J. Wakai, H. Yasuda, K. Koizumi, T. Nomura, Anal. Biochem.179, 336 (1989).
A. Nardi, S. Fanali, F. Foret, Electrophoresis11, 774 (1990).
Y. H. Lee, T.-I. Lin, Electrophoresis17, 333 (1996).
K. L. Larsen, F. Mathiesen, W. Zimmermann, Carbohydr. Res.298, 59 (1997).
D. French, A. O. Pulley, J. A. Effenberger, M. A. Rongvie, M. Abdullah, Arch. Biochem. Biophys.111, 153 (1965).
M. Abdullah, D. French, Arch. Biochem. Biophys.137, 483 (1970).
Y. Sakano, M. Sano, T. Kobayashi, Agric. Biol. Chem.49, 3391 (1985).
T. Shiraishi, S. Kusano, Y. Tsumuyara, Y. Sakano, Agr. Biol. Chem.53, 2181 (1989).
J. Abe, N. Mizowaki, S. Hizukuri, K. Koizumi, T. Utamura, Carbohydr. Res.154, 81 (1986).
J. Abe, S. Hizukuri, K. Koizumi, Y. Kubota, T. Utamura, Carbohydr. Res.176, 87 (1988).
S. Hizukuri, J. Abe, N. Mizowaki, K. Koizumi, T. Utamura, J. Jpn. Soc. Starch Sci.33, 119 (1986).
S. Kitahata, Y. Yoshimura, S. Okada, Carbohydr. Res.159, 303 (1987).
S. Okada, Y. Yoshimura, S. Kitahata, J. Jpn. Soc. Starch Sci.33, 127 (1986).
Lot. No. 95041, Ensuiko Sugar Refining Co., 1995.
R. Kuhn, S. Hoffstetter-Kuhn, Capillary Electrophoresis: Principles and Practice, Springer, Berlin-Heidelberg-New York, 1993.
Á. Buvári, L. Barcza, Acta Chim. Acad. Sci. Hung.126, 455 (1989).
Á. Buvári, J. Szejtli, L. Barcza, Acta Chim. Acad. Sci. Hung.110, 51 (1982).
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Tarnai, M., Szakács, Z., Buvári-Barcza, Á. et al. Capillary electrophoretic separation of mono- and dimaltosyl-β-cyclodextrins and determination of the stability constants of their benzoate complexes. Chromatographia 48, 383–387 (1998). https://doi.org/10.1007/BF02467708
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DOI: https://doi.org/10.1007/BF02467708