Chromatographia

, Volume 48, Issue 11–12, pp 817–822 | Cite as

Crown ether capped cyclodextrin used as stationary phase for capillary gas chromatography

  • Z. R. Zeng
  • M. Liu
Originals

Summary

The solution of a new synthesized compound, mono-6-(1'-benzo-aza-15-crown-5)-2, 3, 6- permethyl-β-cyclodextrin, in the moderately polar polysiloxane OV-1701 was coated onto fused silica capillary column. The chromatographic characteristics including column efficiency, polarity and selectivity were studied. Excellent selectivity for the separation of enantiomers and positional isomers was obtained. The results show that the combined effect between the special caves of β-cyclodextrin and crown ether plays a significant role in the separation.

Key Words

Gas chromatography Crown ether capped cyclodextrin Chiral separations Isomer separations 

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References

  1. [1]
    V. Shurig, J. Chromatogr.666, 111 (1994).CrossRefGoogle Scholar
  2. [2]
    W. A. Konig, S. Lutz, P. Mischnick-Lubbecke, B. Brassant, G. Wenz, J. Chromatogr.447, 193 (1988).CrossRefGoogle Scholar
  3. [3]
    D. W. Armstrong, W. Y. Li, J. Pitha, Anal. Chem.62, 214 (1990).CrossRefGoogle Scholar
  4. [4]
    A. Dietrich, B. Maas, V. Karl, P. Kreis, D. Lehnmann, B. Weber, A. Mosandl, HRC,15, 176 (1992).Google Scholar
  5. [5]
    D. O. Xiao, Y. Ling, R. N. Fu, J. L. Gu, A. Q. Luo, Chromatographia46, 85 (1997).Google Scholar
  6. [6]
    Z. R. Zeng, W. Y. Zhang, Y. M. Zhang, Proceedings of the Tenth Symposium on Chromatography, Nanjing, 1995, p. 297.Google Scholar
  7. [7]
    Z. R. Zeng, M. Liu, Y. O. Ding, Y. Li, R. Y. Zhang, Anal. Chem. (Chinese)26, 940 (1998).Google Scholar
  8. [8]
    C. A. Rouse, A. C. Finlison, J. B. Tarbet, J. C. Pixton, N. M. Djordjevic, K. E. Markides, J. S. Bradshaw, M. L. Lee, Anal. Chem.60, 901 (1988).CrossRefGoogle Scholar
  9. [9]
    C. Y. Wu, C. M. Wang, Z. R. Zeng, X. R. Lu, Anal. Chem.62, 968 (1990).CrossRefGoogle Scholar
  10. [10]
    C. Y. Wu, L. S. Cai, Y. J. Wang, H. M. Hang, Z. R. Zeng, Z. H. Yu, H. Yuan, Chromatographia37, 374 (1993).CrossRefGoogle Scholar
  11. [11]
    Z. R. Zeng, C. Y. Wu, X. H. Fang, Z. F. Huang, Y. T. Wang, J. Chromatogr.589, 368 (1992).CrossRefGoogle Scholar
  12. [12]
    Z. R. Zeng, C. Y. Wu, H. Yan, Z. F. Huang, Y. I. Wang, J. Chromatogr.34, 85 (1992).CrossRefGoogle Scholar
  13. [13]
    I. Willner, Z. Goren, J. Chem. Soc. Commun.24, 1469 (1983).CrossRefGoogle Scholar
  14. [14]
    V. Shurig, H. P. Nowotny, J. Chromatogr.441, 155 (1988).CrossRefGoogle Scholar
  15. [15]
    B. E. Kim, K. P. Lee, K. S. Park, S. H. Lee, J. H. Park, Chromatographia46, 145 (1997).Google Scholar
  16. [16]
    A. Dietrich, B. Mans, A. Mosandl, HRC.18, 152 (1995).Google Scholar
  17. [17]
    I. Hardt, W. A. Konig, J. Microcol. Sep.5, 35 (1993).CrossRefGoogle Scholar
  18. [18]
    T. B. Lu, C. T. Wu, Organic Chem. (Chinese) 312 (1985).Google Scholar
  19. [19]
    Y. Matsui, A. Okimoto, Bull. of Chem. Soc. of Jpn.51, 3030 (1978).CrossRefGoogle Scholar
  20. [20]
    A. Venema, H. Henderiks, R. V. Geest, HRC.14, 676 (1991).Google Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1998

Authors and Affiliations

  • Z. R. Zeng
    • 1
  • M. Liu
    • 1
  1. 1.Department of ChemistryWuhan UniversityWuhanP. R. China

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