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[60] Fulleropyrrolidine functionalized polysiloxane as a stationary phase for capillary gas chromatography

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Summary

In this paper, a new type of [60]fulleropyrrolidine functionalized polysiloxane in which the fullerene moieties were incorporated in the main polysiloxane chain was synthesized the first time and used as a stationary phase for capillary gas chromatography. It demonstrated high column efficiency (2600–2866 plates m−1, on a 250 μm diameter column, for naphthalenek=3.1–3.2, 120 °C), a wide operational temperature range (90–360 °C) and outstanding thermostability. It can be used at 360 °C with a baseline drift of 5∼8×10−15A. Benzene homologues, aromatic hydrocarbons, polar compounds such as alcohols, esters, ketones, anilines and phthalic diesters can be seperated well on this column.

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Authors and Affiliations

  1. Department of Chemistry, Wuhan University, 430072, Wuhan, P. R. China

    Z. -R. Zeng, Y. Liu & Y. -Y. Chen

  2. Wuhan Broadcasting and TV University, 430030, Wuhan, P. R. China

    H. -Y. Ye

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  1. Z. -R. Zeng
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  2. H. -Y. Ye
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  3. Y. Liu
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  4. Y. -Y. Chen
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Zeng, Z.R., Ye, H.Y., Liu, Y. et al. [60] Fulleropyrrolidine functionalized polysiloxane as a stationary phase for capillary gas chromatography. Chromatographia 49, 293–298 (1999). https://doi.org/10.1007/BF02467559

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  • DOI: https://doi.org/10.1007/BF02467559

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