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Evaluation of coelectroosmotic capillary zone electrophoresis for the rapid analysis of twelve aromatic sulphonate compounds

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Summary

Coelectroosmotic capillary zone electrophoresis (CZE) has been investigated as a means of rapid analysis of twelve aromatic sulphonate compounds. The main factors affecting reversal of electroosmotic flow (EOF)—type of osmotic modifier and concentration-were studied. Two types of osmotic modifier, an alkylammonium salt (cetyltrimethylammonium bromide, CTAB) and a cationic polyelectrolyte (hexadimentrine bromide, HDB) were investigated. The composition of the running buffers was optimized according to the characteristics of each osmotic modifier. A concentration of HDB as low as 0.0001% (w/v) was used successfully to provide a stable and reversed EOF.

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Authors and Affiliations

  1. Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Pça Imperial Tarraco 1, 43005, Tarragona, Spain

    M. J. Cugat, F. Borrull & M. Calull

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  1. M. J. Cugat
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  2. F. Borrull
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  3. M. Calull
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Cugat, M.J., Borrull, F. & Calull, M. Evaluation of coelectroosmotic capillary zone electrophoresis for the rapid analysis of twelve aromatic sulphonate compounds. Chromatographia 49, 261–267 (1999). https://doi.org/10.1007/BF02467554

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  • DOI: https://doi.org/10.1007/BF02467554

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