, Volume 47, Issue 9–10, pp 509–514 | Cite as

Porous copolymer of the methacrylic ester of dihydroxydiphenylmethane diglycidyl ether and divinylbenzene as an HPLC packing

  • B. Gawdzik
  • T. Matynia
  • J. Osypiuk


Dimethyldichlorosilane has been used to deactivate the hydroxyl groups present in the skeleton of the porous polymer formed from the methacrylic ester ofp, p′-dihydroxydiphenylmethane diglycidyl ether and divinylbenzene. The influence of chemical modification of the copolymer on its chromatographic behavior has been studied. The retention indices of five homologous series and test compounds were calculated to determine the selectivity of the packings.

Key words

Column liquid chromatography Porous copolymers with hydroxyl groups Chemical modification of phases Selectivity 


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  1. [1]
    H. W. Stuurman, J. Köhler, S. O. Jansson, A. Litzén, Chromatographia23, 341 (1987).CrossRefGoogle Scholar
  2. [2]
    R. M. Smith, Anal. Chem.56, 256 (1984).CrossRefGoogle Scholar
  3. [3]
    A. B. Scholten, H. A. Claessens, J. W. de Haan, C. A. Cramers, J. Chromatogr. A759, 37 (1997).CrossRefGoogle Scholar
  4. [4]
    K. Karch, I. Sebastian, I. Halasz, J. Chromatogr.122, 3 (1976).CrossRefGoogle Scholar
  5. [5]
    P. Jandera, H. Colin, G. Guiochon, Anal. Chem.54, 435 (1982).Google Scholar
  6. [6]
    P. E. Antle, A. P. Goldberg, L. R. Snyder, J. Chromatogr.,321, 1 (1985).CrossRefGoogle Scholar
  7. [7]
    Y. B. Yang, M. Verzele, J. Chromatogr.387, 197 (1987).CrossRefGoogle Scholar
  8. [8]
    J. J. Sun, J. S. Fritz, J. Chromatogr.522, 95 (1990).CrossRefGoogle Scholar
  9. [9]
    C. Hirayama, H. Ihara, S. Nagaoka H. Makise, Chromatographia33, 19 (1992).CrossRefGoogle Scholar
  10. [10]
    B. Gawdzik, T. Matynia J. Osypiuk, Chromatographia44, 25 (1997).CrossRefGoogle Scholar
  11. [11]
    I. Halasz, K. Martin, Ber. Busenges Phys. Chem.79, 731 (1975).Google Scholar
  12. [12]
    B. Gawdzik, J. Gawdzik, U. Czerwinska-Bil, Chromatographia26, 399 (1988).CrossRefGoogle Scholar
  13. [13]
    B. Gawdzik, J. Chromatogr.549, 77 (1991).CrossRefGoogle Scholar
  14. [14]
    F. Nevejans, M. Verzele, J. Chromatogr.350, 145 (1985).CrossRefGoogle Scholar

Copyright information

© Friedr. Vieweg & Sohn Verlagsgesellschaft mbH 1998

Authors and Affiliations

  • B. Gawdzik
    • 1
  • T. Matynia
    • 1
  • J. Osypiuk
    • 1
  1. 1.Faculty of ChemistryMCS UniversityLublinPoland

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