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Ionic strength dependence of heavy metal tartrate complex stabilities

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Summary

Ion chromatography and potentiometry were used for the determination of the stability constants Pb, Zn, Co, Ni, Mn tartrate complexes at different ionic strengths. An extrapolation function based on the Debye-Hückel equation was applied to obtain the thermodynamic stability constants.

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References

  1. A. Martell, R. M. Smith, “Critical stability constants”, Plenum Press, 1989, Volume 6.

  2. F. H. Lin, J. Horvath, J. Chromatogr.589, 185 (1992).

    Article  CAS  Google Scholar 

  3. A. S. Kereichuk, I. M. Churikova, Zhurnal Neorganicheskoi Khimii19, 2154 (1974).

    CAS  Google Scholar 

  4. A. S. Kereichuk, I. M. Churikova, V. I. Tihomirova, Zhurnal Neorganicheskoi Khimii23, 2436 (1978).

    CAS  Google Scholar 

  5. H. Rossotti, F. Rossotii, Opredelenie konstant ustorchivosti i drugikh konstant ravnovesiya v rastvorakh', Mir, Moscow 1965.

    Google Scholar 

  6. P. Janoš, J. Chromatogr641, 229 (1993).

    Article  Google Scholar 

  7. P. Hajos, G. Revesz, J. Chromatogr.640, 15 (1993).

    Article  CAS  Google Scholar 

  8. P. Alumaa, I. Pentšuk, Chromatographia38, 566 (1994).

    Article  CAS  Google Scholar 

  9. P. Janoš, J. Chromatogr. A 699, I (1995).

  10. M. T. Beck, “Chemistry of complex equilibria”, Akademiai Kiado, Budapest, 1970.

    Google Scholar 

  11. A. Neuberger, Proc. Roy. Soc. A158, 68 (1937).

    Google Scholar 

  12. S. Aditya, R. K. Nanda, R. C. Das, Z. Phys. Chem Neue Folge48, 126 (1966).

    CAS  Google Scholar 

  13. A. Martell, R. M. Smith, “Critical stability constants”, Plenum Press, 1974, Volume 3.

  14. “Spravochnik Khimika”, Khimiya Moscow, 1964.

  15. E. A. Burns, F. D. Chang, J. Phys. Chem.63, 314 (1959).

    Article  Google Scholar 

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Alumaa, P., Pentchuk, J. Ionic strength dependence of heavy metal tartrate complex stabilities. Chromatographia 47, 77–80 (1998). https://doi.org/10.1007/BF02466789

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  • DOI: https://doi.org/10.1007/BF02466789

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