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Excess enthalpies of (2,2,4-trimethylpentane or cyclohexane) + methyltert-butyl ether +tert-amyl methyl ether at 25°C

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Abstract

Microcalormetric measurements of excess molar enthalpies at 25°C are reported for two ternary mixtures 2,2,4-trimethylpentane + methyltert-butyl ether +tert-amyl methyl ether and cyclohexane + methyltert-butyl ether +tert-amyl methyl ether. Smooth representations of the results are presented and used to construct constant-enthalpy contours on Roozeboom diagrams. Comparisons of the experimental results with estimates based on the Flory theory of mixtures are also described.

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References

  1. Z. Tong, G. C. Benson, L. L. Wang, and B. C.-Y. Lu,J. Chem. Eng. Data 41, 865 (1996).

    Article  CAS  Google Scholar 

  2. TRC Thermodynamic Tables Hydrocarbons. Thermodynamic Research Center: The Texas A&M University System, College Station TX 77843-3111. 1988: Tables 23-2-(1.203)-a and 23-2-(3.1110)-a.

  3. TRC Thermodynamic Tables Non-Hydrocarbons. Thermodynamic Research Center: The Texas A&M University System, College Station TX 77843-3111. 1988: Tables 23-2-1-(1.2120)-a and 23-2-1-(1.2121)-a.

  4. R. Tanaka, P. J. D'Arcy, and G. C. Benson,Thermochim. Acta 11, 163 (1975).

    Article  CAS  Google Scholar 

  5. F. Kimura, G. C. Benson, and C. J. Halpin,Fluid Phase Equilib. 11, 245 (1983).

    Article  CAS  Google Scholar 

  6. L. Wang, G. C. Benson, and B. C.-Y. Lu,J. Chem. Thermodyn. 24, 1305 (1992).

    Article  CAS  Google Scholar 

  7. S. Zhu, S. Shen, G. C. Benson, and B. C.-Y. Lu,Thermochim. Acta 235, 161 (1994).

    Article  CAS  Google Scholar 

  8. S. Zhu, S. Shen, G. C. Benson, and B. C.-Y. Lu,J. Chem. Eng. Data 39, 302 (1994).

    Article  CAS  Google Scholar 

  9. C. C. Tsao and J. M. Smith,Chem. Eng. Prog. Symp. Ser. No. 7 49, 107 (1953).

    CAS  Google Scholar 

  10. J. W. Morris, P. J. Mulvey, M. M. Abbott, and H. C. Van Ness,J. Chem. Eng. Data 20, 403 (1975).

    Article  CAS  Google Scholar 

  11. P. J. Flory,J. Am. Chem. Soc. 87, 1833 (1965).

    Article  CAS  Google Scholar 

  12. A. Abe and P. J. Flory,J. Am. Chem. Soc. 87, 1838 (1965).

    Article  CAS  Google Scholar 

  13. W. Brostow and J. S. Sochanski,J. Mater. Sci. 10, 2134 (1975).

    Article  CAS  Google Scholar 

  14. L. Wang, G. C. Benson, and B. C.-Y. Lu,Thermochim. Acta 213, 83 (1993).

    Article  CAS  Google Scholar 

  15. A. J. Treszczanowicz and G. C. Benson,Fluid Phase Equilib. 41, 31 (1988).

    Article  CAS  Google Scholar 

  16. A. J. Treszczanowicz and G. C. Benson,Thermochim. Acta 179, 39 (1991).

    Article  CAS  Google Scholar 

  17. S. Zhu, S. Shen, G. C. Benson, and B. C.-Y. Lu,J. Chem. Thermodyn. 26, 35 (1994).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemical Engineering, University of Ottawa, K1N 6N5, Ottawa, Ontario, Canada

    Denis Gravelle, Zhangfa Tong, George C. Benson & Benjamin C. -Y. Lu

  2. Visiting scientist from the Département de Génie Chimique, Université de Sherbrooke, J1K 2R1, Sherbrooke, Québec, Canada

    Denis Gravelle

Authors
  1. Denis Gravelle
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  2. Zhangfa Tong
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  3. George C. Benson
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  4. Benjamin C. -Y. Lu
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Gravelle, D., Tong, Z., Benson, G.C. et al. Excess enthalpies of (2,2,4-trimethylpentane or cyclohexane) + methyltert-butyl ether +tert-amyl methyl ether at 25°C. J Solution Chem 26, 85–95 (1997). https://doi.org/10.1007/BF02439445

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  • DOI: https://doi.org/10.1007/BF02439445

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