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Journal of Sol-Gel Science and Technology

, Volume 9, Issue 2, pp 139–143 | Cite as

Sol-gel synthesis of ge nanocrystals-doped glass and its photoluminescence

  • Masayuki Nogami
  • Yoshihiro Abe
Article

Abstract

Ge nanocrystal-embedded SiO2 glasses were prepared by a sol-gel process. The glasses synthesized through the hydrolysis of Si(OC2H5)4 and GeCl4 were heated in H2 gas atmosphere at 500 to 800°C, in which Ge4+ ions were reduced to precipitate nanosized Ge crystals with the size smaller than 10 nm diameter. Glasses doped with Ge nanocrystals of diameter of ≈5 nm showed the optical absorption edge at ≈2.8 eV and a broad photoluminescence exhibiting the peak at around 2.2 eV. Large Ge crystals precipitated by heating above 800°C showed no photoluminescence.

Key words

Ge nano-crystal photoluminescence doped glass sol-gel 

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Copyright information

© Kluwer Academic Publishers 1997

Authors and Affiliations

  • Masayuki Nogami
    • 1
  • Yoshihiro Abe
    • 1
  1. 1.Department of Materials Science and EngineeringNagoya Institute of TechnologyShowa, NagoyaJapan

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