Skip to main content
SpringerLink
Log in

Structural analogy principle for estimating gas chromatographic retention indices

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

It is shown that using additive schemes complying with the general principle of structural analogy for all molecular transformations is admissible for calculating gas chromatographic retention indices, which are very important analytical parameters for identification of organic compounds. From this viewpoint, we compare the possibilities of using the homomorphism factors and the fit increments of the retention indices of reagents and products in chemical reactions, including those of some topochemically equivalent hypothetical transformations of the structure and composition of organic molecules.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. F. W. Karaseek and R. E. Klement,Basic Gas Chromatography-Mass Spectrometry, Elsevier, Amsterdam (1988).

    Google Scholar 

  2. R. Kaliszan,Quantitative Structure-Chromatographic Retention Relationships, Wiley, New York (1987).

    Google Scholar 

  3. I. G. Zenkevich and L. M. Kuznetsova,Collect. Czech. Chem. Commun.,56, No. 10, 2042–2056 (1991).

    Article  CAS  Google Scholar 

  4. Beilstein Handbuch der Organischen Chemie, Vols. I–XXXI, Berlin (1918).

  5. I. G. Zenkevich,Zh. Strukt. Khim.,35, No. 6, 176–182 (1994).

    CAS  Google Scholar 

  6. I. G. Zenkevich,Abstracts of Papers from the 16th International Symposium on Capillary Chromatography, Vol. 1, Heidelberg (1994), pp. 41–50.

    Google Scholar 

  7. M. S. Vigdergauz, L. V. Semenchenko, V. A. Erzets, and Yu. N. Bogoslovskii,Qualitative Gas Chromatographic Analysis [in Russian], Khimiya, Moscow (1978).

    Google Scholar 

  8. I. G. Zenkevich,J. Ecol. Chem.,3, No. 2, 111–119 (1994).

    Google Scholar 

  9. A. S. Bureiko, I. G. Zenkevich, and B. V. Ioffe,Vestn. Sankt-Peterb. Univ., Ser. Fiz. Khim., No. 1, 57–61 (1992).

    Google Scholar 

  10. Handbuch der Gas-Chromatographie, E. Leibnitz and H. G. Struppe (eds.), Geest and Portig, Leipzig (1970).

  11. T. A. Misharina, R. V. Golovnya, and I. V. Beletskii,Izv. Akad. Nauk, Ser. Khim., No. 7, 1224–1227 (1993).

    Google Scholar 

  12. T. A. Misharina, Sorption of Sulfur- and Oxygen-Containing Compounds in Chromatography: Tendencies and Application for Identification of Volatile Organic Compounds, Author's Abstract of Doctoral Dissertation, Moscow (1995).

  13. I. G. Zenkevich,Zh. Org. Khim.,28, No. 9, 1827–1840 (1992).

    CAS  Google Scholar 

  14. V. M. Potapov,Stereochemistry [in Russian], Khimiya, Moscow (1988).

    Google Scholar 

  15. I. G. Zenkevich and B. V. Ioffe,Interpretation of Mass Spectra of Organic Compounds [in Russian], Khimiya, Leningrad (1986).

    Google Scholar 

  16. I. G. Zenkevich,Abstracts of Papers from the 15th International Symposium on Capillary Chromatography, Vol. 1, Heidelberg (1993), pp. 180–196.

    Google Scholar 

Download references

Authors
  1. I. G. Zenkevich
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Scientific-Research Institute of Chemistry, St. Petersburg University. Translated fromZhurnal Strukturnoi Khimii, Vol. 37, No. 4, pp. 784–795, July–August, 1996.

Translated by L. Smolina

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zenkevich, I.G. Structural analogy principle for estimating gas chromatographic retention indices. J Struct Chem 37, 674–682 (1996). https://doi.org/10.1007/BF02437183

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02437183

Keywords

Search

Navigation