Advertisement

Journal of Structural Chemistry

, Volume 37, Issue 5, pp 767–772 | Cite as

X-ray emission and X-ray photoelectron study of the electronic structure of polymeric cubanocluster compounds Re4−x Mo x S4Te4

  • G. F. Khudorozhko
  • É. A. Kravtsova
  • L. N. Mazalov
  • V. E. Fedorov
  • L. G. Bulusheva
  • I. P. Asanov
  • G. K. Parygina
  • Yu. V. Mironov
Article

Abstract

The electronic structure of cubanocluster compounds of the series Re4−xMoxS4Te4 was studied by X-ray emission and X-ray photoelectron spectroscopy. The electronic structure of the (Re4S4)8+ cluster was calculated by the EHT method. It is shown that replacement of rhenium atoms by molybdenum atoms leads to changes both in the chemical bonds of the Re4S4 cubanocluster fragment and in the bond of the latter with the Te4 fragment.

Keywords

Tellurium Molybdenum Atom ReO2 Tellurium Atom Rhenium Atom 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    S. P. Gubin,Cluster Chemistry. Classification and Structure [in Russian], Nauka, Moscow (1987).Google Scholar
  2. 2.
    T. Shibahara,Coord. Chem. Rev.,123, 73–147 (1993).CrossRefGoogle Scholar
  3. 3.
    S. C. Lee and R. H. Holm,Angew. Chem. Int. Ed. Engl.,29, 840–856 (1990).CrossRefGoogle Scholar
  4. 4.
    S. Harris,Polyhedron,8, No. 24, 2843–2887 (1989).CrossRefGoogle Scholar
  5. 5.
    C. Perrin, R. Chervel, and M. Sergent,C. R. Acad. Sci.,280, No. 14, C949-C951 (1975).Google Scholar
  6. 6.
    C. Perrin, R. Chevrel, and M. Sergent,C. R. Acad. Sci.,281, No. 1, C23-C25 (1975).Google Scholar
  7. 7.
    J. M. Vandenberg and D. Brasen,J. Solid State Chem.,14, 203–208 (1975).CrossRefGoogle Scholar
  8. 8.
    H. B. Yaich, J. C. Jegaden, M. Potel, et al.,ibid.,,51, 212–217 (1984).CrossRefGoogle Scholar
  9. 9.
    C. Perrin, R. Chevrel, and M. Sergent,Solid State Chem.,19, 305–308 (1976).CrossRefGoogle Scholar
  10. 10.
    V. E. Fedorov, Yu. V. Mironov, V. P. Fedin, and Yu. I. Mironov,Zh. Strukt. Khim.,35, No. 1, 157–158 (1994).Google Scholar
  11. 11.
    G. F. Khudorozhko, I. P. Asanov, L. N. Mazalov, et al.,ibid.,,36, No. 6, 94–105 (1995).Google Scholar
  12. 12.
    V. A. Terekhov, V. M. Koshkarev, V. V. Gorbachev, et al.,Fiz. Tverd. Tela,25, 68–71 (1983).Google Scholar
  13. 13.
    A. Cimino,Z. Anorg. Chem.,460, 86–98 (1980).CrossRefGoogle Scholar
  14. 14.
    L. G. Bulusheva, L. N. Mazalov, É. A. Kravtsova, et al.,Zh. Strukt. Khim.,37, No. 2, 383–387 (1996).Google Scholar

Copyright information

© Plenum Publishing Corporation 1997

Authors and Affiliations

  • G. F. Khudorozhko
  • É. A. Kravtsova
  • L. N. Mazalov
  • V. E. Fedorov
  • L. G. Bulusheva
  • I. P. Asanov
  • G. K. Parygina
  • Yu. V. Mironov

There are no affiliations available

Personalised recommendations