Abstract
The results of experimental and theoretical research on thermally stimulated luminescence (TSL) of dosimetric crystals based on anion-defect corundum are systematized. It is shown that all of actually observed features — the dependence of the TSL yield on the heating rate, the dependence of the temperature position of the TSL peak and its shape on the irradiation dose and the heating rate, and the drop in average activation energy within a dosimetric peak — are due to a single process: quenching of the luminescence ofF centers. Evidence is given for a relationship between quenching and the presence of oxygen vacancies of thermochemical or radiative origin. Unusual behavior of Cr3+ ions during thermoluminescence is found. It is suggested that the TSL peak in anion-defect corundum is due to a complex defect formed by oxygen vacancies in various charged states, chromium ions, and possibly the ions of other transition metals.
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L. M. Zatulovskii, D. Ya. Kravetskii, M. S. Aksel'rod, V. S. Kortov, et al., “A means of obtaining profiled monocrystals of aluminum oxide for thermoluminescent dosimetry,” Inventor's Patent No. 1,340,365.
V. S. Kortov, I. I. Mil'man, A. I. Syurdo, M. S. Aksel'rod, and Yu. D. Afonin, “A means of treating the material of a solid-state detector of ioninzing radiation based on aluminum oxide,” Inventor's Patent No. 1,347,729.
V. R. Bichev, V. I. Gotlib, V. L. Grebenshchikov, M. M. Grube, et al., A tissue-equivalent, thermoluminescent detector and the method for its preparation,” Inventor's Patent No. 1,274,472.
M. S. Aksel'rod, V. S. Kortov, I. I. Mil'man, A. I. Munchaev, and A. P. Chirkin, “A material for a solid-state dosimeter,” Inventor's Patent No. 1,072,461.
M. S. Aksel'rod, A. F. Zatsepin, V. S. Kortov, and I. I. Mil'man, “A means of heat treatment of material for a solidstate detector of ionizing radiation based on aluminum oxide,” Inventor's patent No. 993,728.
L. A. Avvakumova, T. S. Bessonova, S. V. Bodyachevskii, and T. I. Gimadova, At. Énerg.,69, No. 5, 309–313 (1990).
M. S. Aksel'rod [Akselrod], V. S. Kortov, D. Ya. Kravetskii [D. J. Kravetsky], and V. I. Gotlib, Radiat. Prot. Dosim.,32, No. 1, 15–20 (1990).
M. S. Aksel'rod (Akselrod), V. S. Kortov, D. Ya. Kravetskii [D. J. Kravetsky], and V. I. Gotlib, Radiat. Prot. Dosim.,33, Nos. 1-4, 119–122 (1990).
D. Curie, Luminescence of Crystals [Russian translation], Inostr. Lit., Moscow (1961).
S. W. S. McKeever, Thermoluminescence of Solids, University Press, Cambridge (1985).
V. S. Kortov, I. I. Milman, V. I. Kirpa, and J. Lesz, Radiat. Prot. Dosim.,55, No. 4, 279–283 (1994).
I. I. Mil'man, V. S. Kortov, and V. I. Kirpa, Fiz. Tverd. Tela,37, No. 4, 1149–1159 (1994).
I. A. Tale, Phys. Status Solidi A,66a, 65–75 (1981).
M. J. Aitken, J. Huxtable, A. G. Wintle, and S. G. E. Bowman, in: International Conference on Luminescence Dosimetry, Krakov (1974), pp. 1005–1019.
B. D. Evans and M. Stapelbroek, Phys. Rev.,B18, No. 12, 7089–7098 (1978).
J. D. Brewer and G. P. Summers, Phys. Lett.,76a, Nos. 3-4, 353–354 (1980).
M. S. Aksel'rod, V. S. Kortov, and I. I. Mil'man, Ukr. Fiz. Zh.,28, No. 7, 1053–1056 (1983).
L. Oster, D. Weiss, and N. Kristianpoller, J. Phys. D: Appl. Phys.,27, 1–5 (1994).
T. S. Bessonova, M. P. Stanislavskii, and V. Ya. Khaimov-Mal'kov, Zh. Prikl. Spektrosk.,16, No. 11, 1961–1965 (1980).
T. S. Bessonova, M. P. Stanislavskii, and V. Ya. Khaimov-Mal'kov, Zh. Prikl. Spektrosk.,30, No. 5, 829–835 (1979).
T. I. Gimadova, T. S. Bessonova, I. A. Tale, L. A. Avvakumova, and S. V. Bodyachevskii, Radiat. Prot. Dosim.,33, Nos. 1-4, 47–50 (1990).
T. S. Bessonova, T. I. Gimadova, I. A. Tale, L. A. Avvakumova, and L. A. Litvinov, Zh. Prikl. Spektrosk.,54, No. 3, 433–437 (1991).
T. S. Bessonova, L. A. Avvakumova, L. A. Gimadova, and I. A. Tale, Zh. Prikl. Spektrosk.,54, No. 2, 258–262 (1991).
A. Niclas and B. Sujak, Acta Phys. Pol.,A48, No. 2, 291–305 (1975).
T. J. Turner and J. H. Crawford, Jr., Solid State Commun.,17, 167–169 (1975).
K. H. Lee, G. E. Holmberg, and J. H. Crawford, Phys. Status Solidi A,39, 669–674 (1977).
S. V. Nikiforov, I. I. Mil'man, and V. S. Kortov, in: Ninth International Conference on Radiation Physics and Chemistry of Inorganic Materials: Abstracts [in Russian], Tomsk (1996), pp. 296–297.
B. Henderson and J. Werts, Defects in the Alkaline Earth Oxides, Taylor and Francis, London (1977), 159 pp.
I. A. Tale, T. M. Piters, M. Barbosa-Flores, Peres-Salas, and M. Springis, Radiat. Meas.,25, No. 4, 57–67 (1996).
D. C. Liu, Phys. Lett.,33A, No. 3, 140–141 (1970).
Additional information
Ural State Technical University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 145–161, November, 1996.
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Kortov, V.S., Mil'man, I.I. Thermally stimulated luminescence of dosimetric α-Al2O3 crystals. Russ Phys J 39, 1122–1134 (1996). https://doi.org/10.1007/BF02436155
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DOI: https://doi.org/10.1007/BF02436155