Abstract
The mechanism by which elementary point defects arise and evolve in beryllium oxide crystals and the latest advances in the dynamics of electron excitations of this compound are considered. Experimental and theoretical results which touch on the generation and evolution of elementary point defects are obtained. The properties of intrinsic and impurity point defects, and the crystal-chemical fundamentals of defect generation, optical and luminescent transitions in them, and color centers are discussed. The electron structure of B2+, Al2+, Zn+, and [Li]0 defects, nonisothermal relaxation of paramagnetic centers, thermostimulated recombination processes, and the concept of the coexistence of two types of self-localized excitons in beryllium oxide, radiative annihilation of which gives rise to luminescence in the UV and far UV bands are considered.
Similar content being viewed by others
References
R. A. Belyaev, Beryllium Oxide [in Russian], Moscow (1986).
S. B. Austerman, J. Nucl. Mater.,14, No. 3, 225–226 (1964).
V. A. Maslov, G. M. Bylov, B. G. Nazurenko, A. V. Kruzhalov, and B. V. Shulgin, Proc. 6th Int. Conference on Crystal Growth, Vol. 3, Moscow (1980), pp. 268–269.
Ch. B. Lushchik and A. Ch. Lushchik, The Decay of Electron Excitations with the Formation of Defects in Solids [in Russian], Moscow (1989).
K. Song and R. T. Williams, Self-Trapped Excitons, Springer Verlag, New York (1993).
V. Yu. Ivanov, V. A. Pustovarov, A. V. Kruzhalov, and S. V. Gorbunov, Fiz. Tverd. Tela,36, No. 9, 2634–2647 (1994).
I. N. Ogorodnikov, V. Yu. Ivanov, and A. V. Kruzhalov, Fiz. Tverd. Tela,36, No. 11, 3287–3298 (1994).
A. Yu. Kuznetsov, V. R. Manozov, and V. V. Myurk, Fiz. Tverd. Tela,27, No. 10, 3030–3036 (1985).
K. N. Giniyatulin, A. V. Kruzhalov, V. A. Maslov, and B. V. Mul'gin, Izv. Akad. Nauk SSSR. Neorgan. Mater.,19, No. 6, 1014–1015 (1983).
I. N. Ogorodnikov, V. Yu. Ivanov, and A. V. Kruzhalov, Radiat. Measurements,24, No. 4, 417–421 (1995).
B. E. Kulyahin, V. A. Lobach, and A. V. Kruzhalov, Fiz. Tverd. Tela,32, No. 12, 3685–3687 (1990).
A. V. Kruzhalov, V. A. Lobach, I. N. Ogorodnikov, and I. R. Rubin, Zh. Prikl. Spektrosk.,51, No. 6, 997–1001 (1989).
V. Yu. Ivanov, I. N. Antsygin, S. V. Gorbunov, A. V. Kruzhalov, and V. A. Maslov, Opt. Spektrosk.,64, No. 4, 949–951 (1988).
S. V. Gorbunov, B. Yu. Yakovlev, A. V. Kruzhalov and V. Yu. Ivanov, Fiz. Tverd. Tela,32, No. 10, 2942–2946 (1990).
V. A. Lobach, I. R. Rubin, A. V. Kruzhalov, B. V. Shul'gin, and V. Yu. Ivanov, Fiz. Tverd. Tela,29, No. 9, 2610–2615 (1987).
V. Ivanov, V. Pustovarov, A. Kruzhalov, and B. Shulgin, Nucl. Instrum. Meth. Phys. Res.,A282, 559–562 (1989).
D. M. Roessler, W. C. Walker, and E. Loh, J. Phys. Chem. Solids,30, No. 2, 157–167 (1969).
V. Yu. Ivanov, A. V. Kruzhalov, and V. L. Petrov, Proc. 8th All-Union Conference on Application of Synchrotron Radiation, Novosibirsk (1987), pp. 291–293.
H. Albrecht and V. Mandeville, Phys. Rev.,94, No. 3, 776–777 (1954).
A. V. Kruzhalov, N. V. Andreev, K. N. Giniyatulin, and S. V. Gorbunov, Khimiya Tverd. Tela, Mezhvuc. Sbornik,6, 57–71 (1983).
V. Yu. Ivanov, É. Kh. Fel'dbach, S. V. Gorbunov, A. V. Kruzhalov, and I. L. Kuusmani, Fiz. Tverd. Tela,30, No. 9, 2728–2738 (1988).
K. N. Giniyatuli, A. F. Malysheva, A. V. Kruzhalov, and T. N. Kyarner, Tr. Inst. Fiz. Akad. Nauk Estonii,53, 71–82 (1982).
L. V. Viktorov, K. P. Gavrilov, A. V. Kruzhalov, et al., Vopr. Atom. Nauki Tekhn., Ser. Fiz. Radiats. Poverzh. Radiats. Materialoved. Khar'kov,3, No. 22, 65–67 (1982).
S. V. Gorbunov, A. V. Kruzhalov, V. Yu. Ivanov, I. N. Ogorodnikov, and B. V. Shulgin, Proc. 5th Int. Conf. on Tunable Lasers (Baykal, 20–22 Sept. 1988), Vol. 1, Novosibirsk (1988), pp. 148–153.
I. M. Ogorodnikov, A. V. Kruzhalov, and V. A. Maslov, Zh. Prikl. Spektrosk.,49, No. 1, 134–136 (1988).
I. N. Ogorodnikov, B. Yu. Ivanov, and A. V. Kruzhalov, Zh. Prikl. Spektrosk.,54, No. 4, 605–610 (1991).
A. P. Zhurakovskii, A. V. Kruzhalov, and A. M.-E. Saar, Fiz. Tverd. Tela,24, No. 6, 1900–1901 (1982).
I. N. Ogorodnikov, V. Yu. Ivanov, and A. V. Kruzhalov, Record of Int. Workshop “Physical Processes in Fast Scintillators: (PHYSCL-94, Sept. 30–Oct. 3, 1994. St. Petersburg, Russia), P. A. Rodnyi and C. W. E. van Eijk (eds.), Delft, The Netherlands, Stratech. Report TUD-SCIR-94-04 (1994), pp. 142–146.
I. N. Ogorodnikov, A. V. Kuzhalov, and V. Yu. Ivanov, Proc. Int. Conf. “Inorganic Scintillators and Their Applications, SCINT95” (Delft, The Netherlands, Aug. 28–Sept. 1, 1995), P. Dorenbos and C. W. E. van Eijk (eds.), Delft Univ. Press (1995), pp. 216–219.
S. Gorbunov, A. Kruzhalov, and M. Springis, Phys. Stat. Sol. B.,141, No. 1, 293–301 (1987).
S. Gorbunov, V. Ivanov, I. Antsigin, Z. Kruzhalov, and B. Shulgin, Radiat. Eff. Defect Solid,119–121, 839–900 (1991).
S. V. Gorbunov, S. V. Kudyakov, V. Yu. Yakovlov, and A. V. Kruzhalov, Fiz. Tverd. Tela,38, No. 1, 214–219 (1996).
S. Gorbunov, S. Kudyakov, B. Shulgin, and V. Yakovlev, Radiat. Eff. Defect Solid,135, 269–274 (1995).
R. H. Bartram, C. E. Swenberg, and J. T. Fournier, Phys. Rev.,139, A941-A952 (1965).
A. Vasil'ev, K. Topornin, and R. Evarestov, Opt. Spektrosk.,48, No. 2, 277–282 (1980).
M. Zamorskii and I. Kityuk, Zh. Prikl. Spektrosk,48, No. 1, 143–146 (1989).
I. N. Ogorodnikov, A. V. Kruzhaolv, and V. A. Maslov, Zh. Tekh. Fiz.,64, No. 3, 100–108 (1994).
Additional information
Ural State Technical University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 11, pp. 76–93, November, 1996.
Rights and permissions
About this article
Cite this article
Kruzhalov, A.V., Ogorodnikov, I.N. & Kudyakov, S.V. Radiative relaxation of low-energy electron excitations and point defects in beryllium oxide. Russ Phys J 39, 1067–1081 (1996). https://doi.org/10.1007/BF02436150
Issue Date:
DOI: https://doi.org/10.1007/BF02436150