, Volume 11, Issue 5–6, pp 468–471 | Cite as

Effects of gamma radiation treatment and plasticizer on alkaline solid polymer electrolytes

  • Mohd Asri Mat Teridi
  • Elias Saion


Alkaline solid polymer electrolyte films have been prepared by the solvent-casting method. Gamma radiation treatment and propylene carbonate plastisizer were used to improve the ionic conductivity of the electrolytes at ambient temperature. The structure of the irradiated electrolytes changes from semi-crystalline to amorphous, indicating that the crosslinking of the polymer has been achieved at a dose of 200 kGy. The ionic conductivity at room temperature of PVA/KOH blend increases from 10−7 to 10−3 Scm−1 after the PVA crosslinking and when the plasticizer concentration was increased from 20 to 30%.


Propylene Ambient Temperature Energy Source Power Generation Ionic Conductivity 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.


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5. References

  1. [1]
    A.A. Mohamad, N.S. Mohamed, Y. Alias and A.K. Arof, Journal of Alloys and Compounds337, 208 (2002).CrossRefGoogle Scholar
  2. [2]
    A. Lewandowski, M. Zajder, E. Frackowiak and F. Beguin, Electrochim. Acta46, 2777 (2001).CrossRefGoogle Scholar
  3. [3]
    A.J. Polak, S.P. Weeks and A.J. Beuhler, Sens. Actuators9, 1 (1986).CrossRefGoogle Scholar
  4. [4]
    P.V. Wright and J.M. Parker, Polymer14, 589 (1973).Google Scholar
  5. [5]
    S.H. Kim, J.Y. Kim, H.S. Kim and H.N. Cho, Solid State Ionics116, 63 (1999).CrossRefGoogle Scholar
  6. [6]
    C.C. Yang, J. Power Sources109, 22 (2002).CrossRefGoogle Scholar
  7. [7]
    A.A. Mohamad, N.S. Mohamed, M.Z.A. Yahya, R. Othman, S. Ramesh, Y. Alias and A.K. Arof, Solid State Ionics156, 171 (2003).CrossRefGoogle Scholar
  8. [8]
    A.K. Arof, N.M. Sabirin, R.H.Y. Subban, A.S.A. Hashim and M.Z.A. Yahya, in: Electrochemical Power Sources: Materials and Characterization (A.K. Arof, N.S. Mohamed, R.H.Y. Subban, A.A.H. Ali and M.Z.A. Yahya, Eds.) Penerbit Universiti Malaya, 2000, 1–10.Google Scholar
  9. [9]
    P.N. Gupta and K.P. Singh, Solid State Ionics86–88, 319 (1996).CrossRefGoogle Scholar
  10. [10]
    R. Mishra and K.J. Rao, J. Eur. Polym.35, 1883 (1999).CrossRefGoogle Scholar
  11. [11]
    A. Bhattacharya, Prog. Polym. Sci.25, 371 (2000).CrossRefGoogle Scholar
  12. [12]
    S. Ramesh and A.K. Arof, Materials Science and Engineering B85, 11 (2001).CrossRefGoogle Scholar
  13. [13]
    A. Lewandowski and K. Skorupska, Polish J. Chem.72, 2635 (1998).Google Scholar
  14. [14]
    B. Wang, S. Mukataka, E. Kokufuta and M. Kodama, Radiation Physics and Chemistry59, 91 (2000).CrossRefGoogle Scholar
  15. [15]
    C.W. Walker and M. Salomon, J. Electrochem. Soc.140, 3409 (1993).Google Scholar

Copyright information

© IfI - Institute for Ionics 2005

Authors and Affiliations

  • Mohd Asri Mat Teridi
    • 1
  • Elias Saion
    • 1
  1. 1.Department of PhysicsUniversity Putra MalaysiaSelangor Darul EhsanMalaysia

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