Conclusion
The experimentally determined total purification factors for palladium relative to silver (first cycle 102, second cycle >103) and rhodium and ruthenium (first cycle >104, second cycle >10) are greater than 105. In connection with the insufficient sensitivity of the atomic absorption method for monitoring and the relatively high value from the control run, we could not determine the true values of the purification factors in some operations of the second extraction cycle and for precipitation of palladosammine. The noted chemical aspects of the behavior of precious metals in extraction systems with petroleum sulfides lead to an estimate of the purification factors for palladium at the 108 level. In particular, the total purification factors increase by 10–100 times when the extraction is carried out in both cycles with W:O=10:1 (F=(W:O)/Dj, where j is the component to be separated [10]). Larger-scale laboratory testing of the proposed flow diagram for recovery and refining of palladium using Ag, Pd, Ru, Rh, and Sb will allow us to experimentally confirm that such estimates are realistic.
Similar content being viewed by others
References
L. V. Arseenkov, B. S. Zakharkin, K. P. Lunichkina, et al., ‘Fission product palladium and rhodium: state in solutions, behavior in regeneration of nuclear power plant fuel, search for selective recovery routes,’ Atomnaya Énergiya,72, No. 5, 461–473 (1992).
V. G. Torgov, V. V. Tatarchuk, I. A. Druzhinina, et al., ‘Rationalization for selection of an extraction system based on petroleum sulfides for recovery of fission product palladium,’ Atomnaya Énergiya,76, No. 6, 478–485 (1994).
K. Kirishima, H. Shibayama, H. Nakahira, et al., ‘Recovery and utilization of valuable metals from spent nuclear fuel. (III) Mutual separation of valuable metals,’ in: Proceedings, International conference on Nuclear Waste Management and Environmental Remediation, Prague (1993), Vol. 1, pp. 667–671.
B. N. Zaitsev, V. A. Korolev, V. P. Popik, et al., ‘Some characteristics of ‘reactor’ palladium,’ Radiokhimiya, No. 3, 411–412 (1988).
V. G. Torgov, ‘Sulfur-containing extraction agents for separation of precious and nonferrous metals,’ Isotopenpräxis,20, No. 9, 148–150 (1984).
V. S. Shaldaev, Recovery of Platinum Metals in Reprocessing Irradiated Fuel Abroad [in Russian], TsNIIatominform, Moscow (1990).
D. Demopoulos, ‘Solvent extraction in precious metals refining,’ J. Metals, June 1986, pp. 13–17.
M. Knothe, ‘Precipitation of palladium(II) as diamminepalladium(II) chloride [Pd(NH3)2Cl2] and the behavior of various impurities,’ Z. Anorg. Allg. Chem., No. 503, 213–223 (1983).
V. I. Belevantsev and L. D. Tsvelodub, ‘Solubility of AgCl in aqueous solutions of HCl and HAuCl4,’ Sibir. Khim. Zh., No. 3, 62–65 (1991).
V. G. Torgov, T. M. Korda, and L. A. Terent'eva, ‘Methods for determination and analysis of gold, silver, and palladium based on extraction by organic sulfides,’ in: Precious Metals: Chemistry and Analysis. Collected Scientific Works, Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR, Novosibirsk (1989), pp. 4–29.
É. N. Gil.'bert, V. G. Torgov, and G. V. Verevkin, ‘Neutron activation determination of gold and palladium using extraction by organic sulfides,’ Izv. Sibir. Otdel. Akad. Nauk SSSR, Ser. Khim. Nauk, No. 7(3), 84–89 (1978).
Author information
Authors and Affiliations
Additional information
Translated from Atomnaya Énergiya, Vol. 80, No. 4, pp. 267–273, April, 1996.
Rights and permissions
About this article
Cite this article
Torgov, V.G., Tatarchuk, V.V., Druzhinina, I.A. et al. Behavior of precious metals in extraction recovery and refining of fission product palladium. At Energy 80, 251–256 (1996). https://doi.org/10.1007/BF02419304
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF02419304