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Mössbauer spectroscopic study of Prussian Blue from different provenances

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Abstract

Ferric ferrocyanides synthesized from different sources of ferric cations and ferrocyanide anions and those derived from ferrous ferricyanide, ferrous ferrocyanide and ferric ferricyanide have been studied using Mössbauer and XRD techniques. Structural information of the effect of the provenance on the properties of the final compound is obtained. Significant correlations between isomer shift and quadrupole splitting of inner and outer iron cations have been observed.

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References

  1. A. Ito, M. Suenagua and K. Ono, J. Chem. Phys. 4(1968)3597.

    Article  ADS  Google Scholar 

  2. H. Inoue, T. Nakazawa, T. Mitsuhashi, T. Shirai and E. Fluck, Hyp. Int. 46 (1989)725.

    Article  ADS  Google Scholar 

  3. A. Ludi and H.U. Güdel, Structure and Bonding 14(1973)1.

    Article  Google Scholar 

  4. P.G. Rasmussen and E.A. Meyers, Polyhedron 3(1984)183.

    Article  Google Scholar 

  5. H.J. Buser, D. Schwarzenbach, W. Petter and A. Ludi, Inorg. Chem. 16(1977)2704.

    Article  Google Scholar 

  6. E. Fluck, H. Inoue and S. Yanagisawa, Z. anorg. allg. Chem. 430(1977)241.

    Article  Google Scholar 

  7. E. Reguera and C. Díaz, in:Proc. 1st Latin-American Conf. Appl. Mössbauer Effect, Rio de Janeiro, 1988, ed. E. Baggio-Saitovitch, E. Galvao da Silva and H.R. Rechenberg (World Scientific, Singapore, 1990), p. 232.

    Google Scholar 

  8. O. Lattimer,The Oxidation States of the Elements and their Potentials in Aqueous Solutions (Prentice-Hall, New Jersey, 1952), p. 35.

    Google Scholar 

  9. J. Danon, in:Applications of the Mössbauer Effect in Chemistry and Solid State Physics, Technical Report Series No. 50 (IAEV, Vienna, 1966), p. 89.

    Google Scholar 

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Authors and Affiliations

  1. Centro Nacional de Investigaciones Cientificas, P.O. Box 6990, Havana, Cuba

    E. Reguera, J. Fernández-Bertrán, A. Dago & C. Díaz

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  1. E. Reguera
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  2. J. Fernández-Bertrán
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  3. A. Dago
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  4. C. Díaz
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Reguera, E., Fernández-Bertrán, J., Dago, A. et al. Mössbauer spectroscopic study of Prussian Blue from different provenances. Hyperfine Interact 73, 295–308 (1992). https://doi.org/10.1007/BF02418604

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  • DOI: https://doi.org/10.1007/BF02418604

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