Abstract
The use of sensitized phosphorescence for visualization of gas phase fluid mixing and the requirements for quantitative imaging measurements are discussed. A model for estimating the molecular-mixing signal's dependence on fluid composition is developed and candidate molecular reactants are considered within the framework of the model. Experiments based on sensitized phosphorescence from both an acetonebiacetyl system and a toluene-biacetyl system show good qualitative agreement with modeled results. It is concluded that quantitative measurements using sensitized phosphorescence are feasible.
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Bates SC (1977) Luminescent visualization of molecular and turbulent transport in a plane shear layer. Ph.D. Thesis, Dept. of Aero, and Astro., Massachusetts Institute of Technology. Also MIT Gas Lab Report 134
Borge MJG;Figuera JM;Luque J (1990) Study of the emission of the excited acetone vapor at intermediate pressures. Spectrochim Acta 46A (4): 617–621
Breidenthal R (1981) Structure in turbulent mixing layers and wakes using a chemical reaction. J Fluid Mech 109: 1–24
Brown RG;Phillips D;Das Gupta G (1974) Mechanisms of electronic energy transfer in the gas phase. J Phys Chem 78 (23): 2407–2414
Burton CS;Noyes WAJr (1968) Electronic energy relaxation in toluene vapor. J Chem Phys 49 (4): 1705–1714
Clemens NT;Mungal MG (1991) A planar Mie scattering technique for visualizing supersonic mixing flows. Exp Fluids 11: 175–185
Clemens NT; Paul PH (1993) Scalar measurements in compressible axisymmetric mixing layers. AIAA 31st Aerospace Sciences Meeting, 11–14 January 1993 (Reno, Nevada), AIAA 93-0220
Cundall RB;Davies AS (1966) The mechanism of the gas phase photolysis of acetone. Proc R Soc London, Ser A, 290: 563–582
Dimotakis PE (1989) Turbulent free shear layer mixing. AIAA 27th Aerospace Sciences Meeting, 9–12 January 1989 (Reno, Nevada), AIAA 89-0262
Garabedian ME;Dows DA (1968) Vapor-phase bimolecular quenching of the triplet state of biacetyl. J Am Chem Soc 90 (10): 2468–2470
Hall JL; Dimotakis PE; Rosemann H (1991) Some measurements of molecular mixing in compressible turbulent shear layers. AIAA 22nd Fluid Dynamics, Plasma Dynamics and Lasers Conference, 24–26 June 1991 (Honolulu, Hawaii), AIAA 91-1719
Hansen DA;Lee EKC (1975) Radiative and nonradiative transitions in the first excited singlet state of symmetrical methyl-substituted acetones. J Chem Phys 62 (1): 183–189
Heicklen J (1959) The fluorescence and phosphorescence of biacetyl vapor and acetone vapor. J Am Chem Soc 81: 3863–3866
Holtzclaw KW;Schuh D (1981) Lifetimes of triplet state alkylbenzenes in the vapor phase. Chem Phys 56: 219–229
Jaffé HH;Orchin M (1962) Theory and applications of ultraviolet spectroscopy. pp 545–552. New York: Wiley
Koochesfahani MM;Dimotakis PE (1986) Mixing and chemical reactions in a turbulent liquid mixing layer. J Fluid Mech 170: 83–112
Lamola AA;Turro NJ (1969) Energy transfer and organic photochemistry. Volume XIV of Technique of Organic Photochemistry, (ed. Weissberger, A.) New York: Interscience Publishers
Lozano A (1992) Laser-excited luminescent tracers for planar concentration measurements in gaseous jets. Ph.D. Thesis, Dept. of Mechanical Engineering, Stanford University. Also HTGL Report T-284
Lozano A;Yip B;Hanson RK (1992) Acetone: a tracer for concentration measurements in gaseous flows by planar laser-induced fluorescence. Exp Fluids 13: 369–376
Mungal MG;Dimotakis PE (1984) Mixing and combustion with low heat release in a turbulent mixing layer. J Fluid Mech 148: 349–382
Richard C;Bouchy M;André J-C;Niclausse M (1978) Radiationless transitions between excited singlet states of biacetyl. Int J Chem Kin 10: 213–226
Sidebottom HW;Badcock CC;Calvert JG;Rabe BR;Damon EK (1972) Lifetime studies of the biacetyl excited singlet and triplet states in the gas phase at 25°. J Am Chem Soc 94: 13–19
Winter M; Hermanson JC; Dobbs GM (1992) Imaging of molecular mixing in a gas-phase turbulent jet by collisional energy-transfer fluorescence. AIAA 30th Aerospace Sciences Meeting, 6–9 January 1992 (Reno, Nevada), AIAA 92-0381
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Yip, B., Lozano, A. & Hanson, R.K. Sensitized phosphorescence: a gas phase molecular mixing diagnostic. Experiments in Fluids 17, 16–23 (1994). https://doi.org/10.1007/BF02412799
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DOI: https://doi.org/10.1007/BF02412799