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Ionics

, Volume 10, Issue 1–2, pp 39–44 | Cite as

AgNbO3 dispersed Ag2SO4 composite for potentiometric SO2 gas sensor application

  • J. B. Randhawa
  • P. Ambekar
  • S. S. Bhoga
  • K. Singh
Article

Abstract

Composite electrolytes of Ag2SO4 is prepared by dispersing fine particles, average particle size <40 microns (350 mesh), of ferroelectric AgNbO3 in varying weight fraction. Enhancement in the conductivity is observed in β-phase of host system. The effect of dispersion on the conductivity, activation energy and transition temperature is studied as a function of weight % of the dispersoid in the host. Two distinct conduction mechanisms, viz. conduction through electrolyte bulk in parallel with conduction along the inter-grain interaction layer (R b ‖R) and perpendicular to the interface (R b ) could be resolved in the frequency range of 5 Hz to 13 MHz at temperatures below 300 °C. The interface interaction is found to be nucleophilic increasing the concentration of Ag+ vacancies at the interface. Potentiometric SO2 gas sensors are tested with this composite electrolyte as an auxiliary phase.

Keywords

Activation Energy Average Particle Size Weight Fraction Renewable Energy Source Electrical Power Generation 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© IfI - Institute for Ionics 2004

Authors and Affiliations

  • J. B. Randhawa
    • 1
  • P. Ambekar
    • 1
  • S. S. Bhoga
    • 1
  • K. Singh
    • 1
  1. 1.Department of PhysicsNagpur University CampusNagpurIndia

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