Abstract
The effect of a composite of graft copolymers of polycaproamide and polyglycidyl methacrylate on the reaction rate of α-oxide groups with thiourea was determined. A supermolecular effect in the heterophase macromolecular reaction of transformation of α-oxide groups with thiourea was revealed. It was found that the degree of polymer-analog transformations of α-oxide groups into thiirane groups in PCA-PGMA graft copolymers is on the level of 55–70%.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Z. A. Rogovin, The Chemistry of Cellulose [in Russian], Khimiya, Moscow (1972).
Z. A. Zazulina, T. V. Druzhinina, and A. A. Konkin, Principles of Chemical Fibre Technology [in Russian], Khimiya, Moscow (1985).
G. I. Kudryavtsev (ed.), Reinforcing Chemical Fibres for Composite Materials [in Russian], Khimiya, Moscow (1992).
N. Yu. Mosina, T. V. Druzhinina, et al., Khim. Volokna, No. 3, 6–9 (1996).
D. G. Sil'chenkov, I. N. Illarionov, and M. P. Zverev, Khim. Volokna, No. 2, 15–17 (1995).
T. V. Nemilova, L. V. Emets, et al., Khim. Volokna, No. 2, 22–27 (1996).
N. Yu. Mosina, T. V. Druzhinina, and L. S. Gal'braikh, Khim. Volokna, No. 5, 14–17 (1992).
I. N. Zamorova, Yu. E. Kazakevich, et al., Zh. Prikl. Khim.,65, No. 3, 686–691 (1992).
Author information
Authors and Affiliations
Additional information
Translated from Khimicheskie Volokna, No. 5, pp. 13–16, September–October, 1997.
Rights and permissions
About this article
Cite this article
Druzhinina, T.V., Tvorogova, M.M. & Mosina, N.Y. Reaction of α-oxide groups in graft copolymers of polycaproamide and polyglycidyl methacrylate with thiourea. Fibre Chem 29, 282–286 (1997). https://doi.org/10.1007/BF02408149
Issue Date:
DOI: https://doi.org/10.1007/BF02408149