Abstract
Mössbauer spectra of AlTFe-alloys with T=Cr or Mn, show a quadrupole splitting QS≈0.4 mm/s. This shows that the iron atom is not in an icosahedral site. In order to investigate the local symmetry further, we applied an external magnetic field Hext≈5T, so that the asymmetry parameter ν can be obtained. Using a one site approximation the results are: ν=0.7 for decagonal Al7(Mn0.7Fe0.3)2 and ν=0.8 for icosahedral Al6Cr0.7Fe0.3. This means that the iron atoms are in sites with a symmetry lower than axially symmetric. Most of the vertices in a Penrose lattice show such a symmetry.
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Xu, R., Werkman, R.D., Vince, I. et al. Local symmetry in some quasicrystalline AlTFe alloys. Hyperfine Interact 45, 403–407 (1989). https://doi.org/10.1007/BF02405906
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DOI: https://doi.org/10.1007/BF02405906