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Mössbauer spectroscopy of R2Fe14B and related compounds

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Abstract

The Mössbauer Spectroscopy (MBS) has been widely used in the last 4 years for the study of the recently discovered ternary compounds R2Fe14B where R means Y, Th or a rare earth element. The strong interest for this class of intermetallics arose drastically after the discovery of the exceptional properties of Nd2Fe14 as an ideal material for permanent magnet applications.

The newest results about hyperfine fields BHF, quadrupole splitting EQ and isomer shifts I.S. at the 6 crystallographically different Fe sites and at the 2 R sites in the R2Fe14B and their impact on the understanding of the local magnetic moments and magnetocrystalline anisotropy will be reviewed.

In the case of RFe12−xMx compounds where M=V, Ti, Si, Mo, W, Cr, complex Mössbauer spectra were obtained because of the presence of 3 crystallographically inequivalent Fe sites and the presence of differents amounts of the M component on one or more of these sites.

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References

  1. M. Sagawa, S. Fujimura, N. Togawa, H. Yamamoto and Y. Matsuura, J. Appl. Phys. 55 (1984) 2083.

    Article  ADS  Google Scholar 

  2. J.J. Croat, J.F. Herbst, R.W. Lee and F.E. Pinkerton, J. Appl. Phys. 55 (1984) 2078.

    Article  ADS  Google Scholar 

  3. N.F. Chaban, Yu.B. Kuz'ma, N.S. Bilonizhko, O.O. Kaclmar and N.V. Petrov, Depov. Akad. Nauk. USSR Ser A Fiz. Mat. Tekh. Nauki 10 (1979) 873.

    Google Scholar 

  4. R. Furchart, Ph. l'Heritier, P. Dalmas de Reotier, D. Furchart, P. Wolfers, J.M.D. Coey, L.P. Ferreira, R. Guilleu, P. Vulliet and A. Yaouanc, J. Phys. F.

  5. K.H.J. Buschow, Mat. Sci. Rep. 1 (1986) 1.

    Article  Google Scholar 

  6. P. Deppe, Ph. D. Dissertation (Bochum, 1987).

  7. J.F. Herbst, J.J. Croat, F.E. Pinkerton and W.B. Yelon, Phys. Rev. B 29 (1984) 4176.

    Article  ADS  Google Scholar 

  8. D. Givord, H.S. Li and J.M. Moreau, Solid State Commun. 50 (1984) 497.

    Article  Google Scholar 

  9. C.B. Shoemaker and D.P. Shoemaker, Acta Cryst. C 40 (1984) 1665

    Article  Google Scholar 

  10. M. Rosenberg, P. Deppe and H. Stadelmaier, Hyp. Int. 28 (1986) 503.

    Article  Google Scholar 

  11. B. Szpunar and A. Szpunar, J. Appl. Phys. 57 (1985) 4130.

    Article  ADS  Google Scholar 

  12. M. Rosenberg, P. Deppe, M. Wojcik and H. Stadelmaier, J. Appl. Phys. 57 (1985) 4124.

    Article  ADS  Google Scholar 

  13. M. Rosenberg, P. Deppe, K. Erdmann, M. Sostarich and H. Stadelmaier, J. Magn. Magn. Mat. 54–57 (1986) 599.

    Article  Google Scholar 

  14. K. Erdmann, M. Rosenberg and S. Hirosawa, Proc. AMPERE Conf. Rome (1986) 226.

  15. K. Erdmann, P. Deppe, M. Rosenberg and K.H.J. Buschow, J. Appl. Phys. 61 (1987) 4340.

    Article  ADS  Google Scholar 

  16. K. Erdmann, M. Rosenberg and K.H.J. Buschow, J. Appl. Phys. 63 (1988) 4116.

    Article  ADS  Google Scholar 

  17. K. Erdmann, Th. Sinnemann, M. Rosenberg and K.H.J. Buschow, to appear in J. Less-Common Met. (1988).

  18. D. Givord, H.S. Li and F. Tasset, J. Appl. Phys. 57 (1985) 4100.

    Article  ADS  Google Scholar 

  19. J.F. Herbst and W.B. Yelon, J. Appl. Phys. 54–57 (1986) 570.

    Google Scholar 

  20. Z. Guand, W.Y. Ching, Phys. Rev. B. 33 (1986) 2868.

    Article  ADS  Google Scholar 

  21. Z. Gu and W.Y. Ching, Phys. Rev. B. 36 (1987) 8530.

    Article  ADS  Google Scholar 

  22. D.J. Sellmyer, M.A. Engelhardt, S.S. Jaswal and A.J. Arko Phys. Rev. Lett. 60 (1988) 2077.

    Article  ADS  Google Scholar 

  23. Y.C. Yang, D.E. Tharp, G.J. Long, O.A. Pringle and W.J. James, J. Appl. Phys. 61 (1987) 4343.

    Article  ADS  Google Scholar 

  24. O.A. Pringle, G.K. Marasingle, G.J. Long, W.J. James, W.B. Yelon, D. Xie and F. Grandjeau, Paper DA-10, The 4th Joint MMM-Intermag Conference, Vancouver, July 12–15, 1988.

  25. D.E. Tharp, G.J. Long, O.A. Pringle, G.K. Marasinghe, W.J. James and F. Grandjeau, Paper EA-11, The 4th Joint MMM-Intermag Conference, Vancouver, July 12–15, 1988.

  26. S. Dai, A.H. Morrish, X.Z. Zhou, B.P. Hu and S.G. Zhang, J. Appl. Phys. 63 (1988) 3722.

    Article  ADS  Google Scholar 

  27. H.M. van Noort and K.H.J. Buschow, J. Less-Common Met. 113 (1985) L9.

    Article  Google Scholar 

  28. P. Deppe, M. Rosenberg, S. Hirosawa and M. Sagawa, J. Appl. Phys. 61 (1987) 4337.

    Article  ADS  Google Scholar 

  29. J.F. Herbst and W.B. Yelon, J. Appl. Phys. 60 (1986) 4224.

    Article  ADS  Google Scholar 

  30. M. Boge, J.M.D. Coey, G. Czjzek, D. Givord, C. Jeandrey, H.S. Li and J.L. Oddou, Solid State Commun. 55 (1985) 295.

    Article  Google Scholar 

  31. M. Boge, G. Czjzek, D. Givord, C. Jeandey, H.S. Li and J.L. Oddou, J. Phys. F: Met. Phys. 16 (1986) L67

    Article  ADS  Google Scholar 

  32. N.C. Koon, M. Abe, E. Callen, B.N. Das, S.H. Liou, A. Martinez and R. Segnan, J. Magn. Magn. Mat. 54–57 (1986) 593.

    Article  Google Scholar 

  33. H. Onodera, H. Yamauchi, M. Yamada, H. Yamamoto, M. Sagawa and S. Hirosawa, J. Magn. Magn. Mat. 68 (1987) 15.

    Article  ADS  Google Scholar 

  34. D.B. de Mooij and K.H.J. Buschow, Philips J. Res. 42 (1987) 246.

    Google Scholar 

  35. D.B. de Mooij and K.H.J. Buschow, J. Less-Common Met. 136 (1988) 207.

    Article  Google Scholar 

  36. F.R. de Boer, Huang Ying-Kai, D.B. de Mooij and K.H.J. Buschow, J. Less-Common Met. 135 (1987) 199.

    Article  Google Scholar 

  37. P.C.M. Gubbens, A.M. van der Kraan and K.H.J. Buschow, Hyp. Int. 40 (1988) 389.

    Article  Google Scholar 

  38. H.S. Li, B.P. Hu and J.M.D. Coey, Solid State Commun. 66 (1988) 133.

    Article  Google Scholar 

  39. R.B. Helmboldt and K.H.J. Buschow, J. Less-Common Met.

  40. K.H.J. Buschow, J. Appl. Phys. 63 (1988) 3130.

    Article  ADS  Google Scholar 

  41. Th. Sinnemann, M. Rosenberg and K.H.J. Buschow, to be published in J. Less-Common Met.

  42. Th. Sinnemann, K. Erdmann, M. Rosenberg and K.H.J. Buschow, Paper B28 presented at NMM 88 Munich, Aug. 1–4, 1988.

  43. O. Mose, L. Pareti and M. Solzi, Solid State Commun. 66 (1988) 465

    Article  Google Scholar 

  44. M. Solzi, L. Pareti, O. Moze and W.I.F. David, to be published in J. Appl. Phys.

  45. O. Moze, P.A. Algarabel, M.R. Ibarra, M. Solzi and L. Pareti, to be published in Solid State Commun.

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Authors and Affiliations

  1. Ruhr-Universität Bochum, NB 03-34, PB 102148, 4630, Bochum, BR Deutschland

    M. Rosenberg, P. Deppe & Th. Sinnemann

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  1. M. Rosenberg
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  2. P. Deppe
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  3. Th. Sinnemann
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Rosenberg, M., Deppe, P. & Sinnemann, T. Mössbauer spectroscopy of R2Fe14B and related compounds. Hyperfine Interact 45, 3–19 (1989). https://doi.org/10.1007/BF02405869

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