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The study of Ziegler-Natta type organometallic catalysts in hydrogenation

  • Surface Phenomena, Catalysis, Corrosion
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Abstract

The system, Fe(C17H35COO)3-Al(C2H5)3, has been studied directly in the process of cyclohexane and phenylacetylene hydrogenation. It is shown that the system composition can vary in the course of the catalytic process. The effect of unsaturated compounds on the system composition depends on their ability to serve as ligands.

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References

  1. A.R. Brodskii, V.F. Vosdvizhenskii, N.F. Noskova, A.S. Khlystov, O.M. Pakhorukova and D.V. Sokolskii, J. Organomet. Chem. 173, No. 2 (1979) 325; 179, No. 1 (1979) 139.

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  2. A.R. Brodskii, N.F. Noskova, D.V. Sokolskii and A.S. Khlystov, Dokl. AN SSSR. 268, No. 6 (1983) 1430.

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  3. A.R. Brodskii, N.F. Noskova and D.V. Sokolskii, Dokl. AN SSSR. 278, No. 6 (1984) 1386.

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Authors and Affiliations

  1. D. V. Sokolskii Institute of Organic Catalysis and Electrochemistry, Academy of Sciences of Kazakh SSR, 142 K. Marx, 480100, Alma-Ata, USSR

    A. R. Brodskii & N. F. Noskova

Authors
  1. A. R. Brodskii
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  2. N. F. Noskova
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Brodskii, A.R., Noskova, N.F. The study of Ziegler-Natta type organometallic catalysts in hydrogenation. Hyperfine Interact 57, 1765–1768 (1990). https://doi.org/10.1007/BF02405719

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  • DOI: https://doi.org/10.1007/BF02405719

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