Skip to main content
Log in

Electron microscopy of lithium ferrites. Precipitation of LiFe5O8 in α-LiFeO2

  • Papers
  • Published:
Journal of Materials Science Aims and scope Submit manuscript

Abstract

α-LiFeO2, which has the rocksalt structure, loses lithium when it is heated in air at temperatures bove about 1000°C. The consequent non-stoichiometry is retained by rapid quenching, but slower rates of cooling are accompanied by precipitation of the ferri-magnetic spinel, LiFe5O8. The size, shape, and structure of the precipitate particles depends upon the thermal treatment of the samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. M. E. Fine in “The Chemistry of Extended Defects in Non-metallic Solids” (L. Eyring and M. O'Keeffe, eds., North Holland, 1969).

  2. K. N. Woods andM. E. Fine,J. Am. Ceram. Soc. 52, (1969) 186.

    CAS  Google Scholar 

  3. E. Posnjak andT. Barth,Phys. Rev. 38 (1931) 2234.

    Article  CAS  Google Scholar 

  4. A. Hoffmann,Naturwiss. 26 (1938) 431.

    Article  CAS  Google Scholar 

  5. P. B. Braun,Nature 170 (1952) 1123.

    CAS  Google Scholar 

  6. M. Brunel andF. De Bergevin,J. Phys. Chem. Solids 30 (1969) 2011.

    Article  CAS  Google Scholar 

  7. G. P. Wirtz andM. E. Fine,J. Am. Ceram. Soc. 51 (1968) 402.

    CAS  Google Scholar 

  8. D. E. Cox, G. Shirane, P. A. Flinn, S. L. Ruby, andW. J. Takei,Phys. Rev. 132 (1963) 1547.

    Article  CAS  Google Scholar 

  9. J. C. Anderson, S. K. Dey, andV. Halpern,J. Phys. Chem. Solids 26 (1965) 1555.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Allpress, J.G. Electron microscopy of lithium ferrites. Precipitation of LiFe5O8 in α-LiFeO2 . J Mater Sci 6, 313–318 (1971). https://doi.org/10.1007/BF02403098

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02403098

Keywords

Navigation