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Reactivities of heterocyclic compounds in niration. 4. Kinetics and mechanism of nitration of 2-picrylaminopyridine in sulfuric acid

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Abstract

The kinetics of nitration of 2-picrylaminopyridine with nitric acid in 85– 96% sulfuric acid were studied by a spectrophotometric method. It is shown that 2-picrylaminopyridine undergoes the reaction in the protonated form. The kinetic parameters of the nitration and the relative reactivity as compared with benzene were calculated.

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Authors and Affiliations

  1. S. M. Kirov Kazan Institute of Chemical Technology, 420015, Kazan

    G. P. Sharnin, I. F. Falyakhov & F. G. Khairutdinov

Authors
  1. G. P. Sharnin
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  2. I. F. Falyakhov
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  3. F. G. Khairutdinov
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Additional information

See [1] for communication 3.

Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 3, pp. 363–365, March, 1980.

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Sharnin, G.P., Falyakhov, I.F. & Khairutdinov, F.G. Reactivities of heterocyclic compounds in niration. 4. Kinetics and mechanism of nitration of 2-picrylaminopyridine in sulfuric acid. Chem Heterocycl Compd 16, 272–274 (1980). https://doi.org/10.1007/BF02401725

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  • DOI: https://doi.org/10.1007/BF02401725

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