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Hyperfine Interactions

, Volume 41, Issue 1, pp 767–770 | Cite as

Structural site occupation of iron within 2∶1 dioctahedral phyllosilicates studied by57Fe Mössbauer spectroscopy

  • C. M. Cardile
Mineralogy Geology Archaeology

Abstract

A Mössbauer spectroscopic study of a range of Fe-containing 2∶1 dioctahedral phyllosilicates has indicated that Fe substitution shows a consistent pattern. Samples with a lowerIVFe3+ content directVIFe3+ substitution to essentially trans-OH sites; intermediateIVFe3+ content samples directVIFe3+ substitution to both cis-and trans-OH sites; highIVFe3+ content directsVIFe3+ to cis-OH sites only.

Keywords

Iron Spectroscopy Thin Film Spectroscopic Study Consistent Pattern 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© J.C. Baltzer A.G., Scientific Publishing Company 1988

Authors and Affiliations

  • C. M. Cardile
    • 1
  1. 1.Chemistry DivisionDepartment of Scientific and Industrial ResearchPetoneNew Zealand

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