Skip to main content
Log in

The Knight shift of francium in mercury

  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

For Fr in Hg an extremely small Knight shift has been found as compared to the shift known for an alkali metal host. It indicates an almost complete loss of the outer s-electron of the alkali atom Fr when embedded in liquid mercury. This may be understood as a consequence of the small ionization energy of the Fr atom in comparison with the large work function of mercury.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. H. Haas, H.-E. Mahnke, W.G. Shen, Ch. Stenzel, Hyp. Int.34 (1987) 543

    Article  Google Scholar 

  2. F. Hensel, in: Ionic liquids, molten salts and polyelectrolytes, eds. K.-H. Bennemann, F. Brouers, D. Quitmann, Lecture Notes in Physics172 (1982) 13

  3. W. van der Lugt, J. Noncryst. Sol.61/62 (1984) 187

    Article  Google Scholar 

  4. P. Heitjans et al., Hyp. Int.15/16 (1983) 569

    Article  Google Scholar 

  5. J.R. Beene et al., Hyp. Int.3 (1977) 397

    Article  Google Scholar 

  6. G.C. Carter, L.H. Bennett, D.J. Kahan, Metallic shifts in NMR, in: Progress in Materials Science, ed. B. Chalmers, J.W. Christian, T.B. Massalski (Pergamon Press 1977)

  7. S.V. Andreev, V.S. Lelokhov, V.I. Mishin, Phys. Rev. Lett.,59 (1987) 1274

    Article  ADS  Google Scholar 

  8. H.B. Michaelson, J. Appl. Phys.21 (1950) 536

    Article  Google Scholar 

  9. R. Hultgren, Selected Values of Thermodynamic Properties of Metals and Alloys, Am. Soc. Metals (New York) 1973

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Haas, H., Stenzel, C., Mahnke, H.E. et al. The Knight shift of francium in mercury. Hyperfine Interact 60, 675–678 (1990). https://doi.org/10.1007/BF02399843

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02399843

Keywords

Navigation