Skip to main content
Log in

Die elektronenstruktur der ethen-nickel π-komplexe the electronic structure of ethylene nickel π-complexes

  • Original Investigations
  • Published:
Theoretica chimica acta Aims and scope Submit manuscript

Abstract

Nickel(0)-olefine π-complexes such as Ni(C2H4)3 and Ni(C2H4)(PR3)2 [6] prepared by conventional ligand replacement reaction are diamagnetic and stable up to room temperature. Similar π-complexes e.g. Ni(C2H4) n (withn = 1, 2 or 3) generated by cryo-condensation technique [3] may exist in a paramagnetic state which derives from the triplet ground state of the atomic nickel. The stability of (η2-ethylene) nickel has been explained byab initio-MO calculations relating the energies of the complexes to different terms (1 S and3 F) of the nickel atom.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literatur

  1. Heck, R. F.: Organotransition metal chemistry, a mechanistic approach. New York: Academic Press 1974

    Google Scholar 

  2. Power, W. J., Ozin, G. A.: Adv. Inorg. Chem. Radiochem.23, 79 (1980)

    CAS  Google Scholar 

  3. Ozin, G. A., Power, W. J.: Inorg. Chem.17, 2836 (1978)

    Article  CAS  Google Scholar 

  4. Schaefer III, H. F.: THEOCHEM.1, 117 (1981); Pitzer, R. M., Schaefer, H. F.: J. Am. Chem. Soc.101, 7176 (1979)

    Article  CAS  Google Scholar 

  5. Upton, T. H., Goddard, W. A.: J. Am. Chem. Soc.100, 321 (1978)

    Article  CAS  Google Scholar 

  6. Fischer, K., Jonas, K., Wilke, G.: Angew. Chem.85, 620 (1973)

    CAS  Google Scholar 

  7. Herberhold, M.: Metal π-complexes, Vol. II, Amsterdam: Elsevier Publ. Comp. 1972

    Google Scholar 

  8. Almlöf, J.: The MOLECULE computer program. Stockholm 1974

  9. Roos, B., Veillard, A., Vinot, G.: Theoret. Chim. Acta (Berl.),20, 1 (1971)

    Article  CAS  Google Scholar 

  10. Hay, P. J.: J. Chem. Phys.66, 4377 (1977)

    Article  CAS  Google Scholar 

  11. Akermark, B., Almemark, M., Almlöf, J., Bäckvall, J. E., Roos, B., Stogard, A.: J. Am. Chem. Soc.99, 4617 (1977)

    Article  CAS  Google Scholar 

  12. Roos, B., Siegbahn, P.: Theoret. Chim. Acta (Berl.),17, 203 (1970)

    Google Scholar 

  13. Ittel, S. D., Ibers, J. A.: Adv. Organomet. Chem.14, 33 (1976)

    Article  CAS  Google Scholar 

  14. Dewar, M. J. S.: Bull. Soc. Chim. Fr.18, C 79 (1951)

    Google Scholar 

  15. Chatt, J., Duncanson, L.: J. Chem. Soc. 2939 (1953)

  16. Roos, B., Salez, C., Veillard, A., Clementi, E.: A general program for calculation of atomic SCF orbitals by the expansion method. IBM Research Report 1968

  17. Basch, H., Newton, M. D., Moskowitz, J. W.: J. Chem. Phys.69, 584 (1978)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bögel, H. Die elektronenstruktur der ethen-nickel π-komplexe the electronic structure of ethylene nickel π-complexes. Theoret. Chim. Acta 63, 395–399 (1983). https://doi.org/10.1007/BF02399168

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02399168

Key words

Navigation