Skip to main content
SpringerLink
Log in

119Sn and151Eu Mössbauer study of EuBa2(Cu1-xSnx)3O7-y perovskites

  • Various Applications
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Eu and Sn Mössbauer spectroscopy was used to study EuBa2(Cu1-xSnx)3O7-y metallic oxides. The spectra are characteristic for EuIII and SnIV states in all cases. The existence of at least two different Sn states was determined by decomposition of the Sn Mössbauer spectra. These Sn sites can be associated with nonequivalent Cu sites replaced by Sn atoms in the perovskite type lattice. Anomalous changes were observed in the isomer shifts and area fractions in the spectra measured at room temperature and at 77 K. It can be interpreted assuming low temperature phase transformation and phonon softening. Time dependent changes were found in the Sn spectra recorded at 77 K in the case of highest Sn concentration. The observed changes are consistent with a transitional stage of the low temperature phase transformation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. P.H. Hor, R.L. Meng, Y.Q. Wang, L. Gao, Z.J. Huang, J. Bechtold, K. Forster, C.W. Chu, Phys. Rev. Lett., 58 (1987) 1891.

    Article  ADS  Google Scholar 

  2. T. Takabatake, Y. Nakazawa, M. Ishikawa, J. Jap. Appl. Phys., 26 (1987) L1231.

    Article  Google Scholar 

  3. I. Kirschner, J. Bánkuti, M. Gál, K. Torkos, Phys. Rev. B 36 (1987) 2313.

    Article  ADS  Google Scholar 

  4. C.Y. Huang, L.J. Ories, P.H. Hor, R.L. Meng, C.W. Chu, R.B. Frankel, Nature, 32B (1987) 403.

    Article  ADS  Google Scholar 

  5. I. Kirschner, J. Bánkuti, M. Gál, K. Iorkos, K.G. Solymos, G. Horváth, Europhys. Lett., 3 (1987) 1305.

    ADS  Google Scholar 

  6. A. Durmand, J.C.H. Spence, Nature 329 (1987) 425.

    Article  ADS  Google Scholar 

  7. A. Vértes, E. Kuzmann, Z. Homonnay, M. Gál, K. Torkos, Hyp. Int., 42 (1988) 1247.

    Google Scholar 

  8. E. Kuzmann, Z. Homonnay, A. Vértes, M. Gál, K. Torkos, B. Csákvári, K. Solymos, G. Horváth, J. Bánkuti, I. Kirschner, L. Korecz, Phys. Rev. B, BN3617 (1988).

  9. J. Giapintzakis, J.M. Matykiewicz, C.W. Kimball, A.E. Owight, B.D. Dunlap, M. Slaski, F.Y. Fradin, Phys. Lett., A121 (1987) 307.

    Article  ADS  Google Scholar 

  10. P. Boolchand, R.N. Enzweller, I. Zitkovsky, J. Wells, W. Bresser, D. McDaniel, R.L. Meng, P.H. Hor, C.W. Chu, C.Y. Huang, Phys. Rev., B 37 (1988).

Download references

Author information

Authors and Affiliations

  1. Laboratory of Nuclear Chemistry, Eötvös University, Budapest, Hungary

    E. Kuzmann, Z. Homonnay & A. Vértes

  2. Department of Low Temperature Physics, Eötvös University, Budapest, Hungary

    I. Kirschner, G. Horváth & J. Bánkuti

  3. Department of General and Inorganic Chemistry, Eötvös University, Budapest, Hungary

    M. Gál, K. Torkos, B. Csákvári & K. Solymos

  4. Department of Atomic Physics, Eötvös University, Budapest, Hungary

    L. Korecz

Authors
  1. E. Kuzmann
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Z. Homonnay
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Vértes
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I. Kirschner
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Gál
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. K. Torkos
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. B. Csákvári
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. K. Solymos
    View author publications

    You can also search for this author in PubMed Google Scholar

  9. G. Horváth
    View author publications

    You can also search for this author in PubMed Google Scholar

  10. J. Bánkuti
    View author publications

    You can also search for this author in PubMed Google Scholar

  11. L. Korecz
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Kuzmann, E., Homonnay, Z., Vértes, A. et al. 119Sn and151Eu Mössbauer study of EuBa2(Cu1-xSnx)3O7-y perovskites. Hyperfine Interact 46, 747–752 (1989). https://doi.org/10.1007/BF02398268

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02398268

Keywords

Search

Navigation