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Hyperfine Interactions

, Volume 65, Issue 1–4, pp 891–900 | Cite as

Hyperfine anisotropy and crystal field effects in Mu adducts to naphthalene

  • Ivan D. Reid
  • Emil Roduner
Molecular Structure and Dynamics, Muonium Chemistry
  • 31 Downloads

Abstract

Muonated cyclohexadienyl type radicals have been studied in a naphthalene single crystal using the standard transverse-field μSR technique. Muonium addition occurs at both the α and the β positions. Because of the multiplicity and weakness of the lines in the Fourier spectrum, special techniques were developed to allow the signals to be found and identified. The isotropic hyperfine coupling constants show large shifts from the solution values, with significant anisotropy in the hyperfine tensors. The results for the α radicals are similar to those observed for protonated α-hydronaphthyl radicals, but isotope effects are evident. Based on the hyperfine tensor directions and geometrical considerations, each radical has been assigned to a specific muon site within the crystal.

Keywords

Naphthalene Crystal Field Isotope Effect Fourier Spectrum Hyperfine Coupling 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© Scientific Publishing Company 1990

Authors and Affiliations

  • Ivan D. Reid
    • 1
  • Emil Roduner
    • 1
  1. 1.Physikalish-Chemisches Institut der Universität ZürichZürichSwitzerland

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