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Mössbauer study on the gamma radiolysis of anhydrous cesium tris (oxalato) ferrate(III)

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Abstract

The final product of the gamma radiolysis of anhydrous cesium tris(oxalato) ferrate(III) has been identified by Mössbauer spectroscopy as Cs2Fe(ox)2. The radiolytic decomposition proceeds as a first-order process due to the original compound depletion and to the radiolytic stability of the ferrous compound. Lamb-Mössbauer factors measurements indicate that the recoilless fractions of the iron species are practically unaffected by the radiolysis.

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References

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Authors and Affiliations

  1. Laboratoire de Chimie Inorganique et Nucléaire, Université Catholique de Louvain Chemin du Cyclotron, 2, B-1348, Louvain-la-Neuve, Belgium

    J. Ladriere, V. Senterre & D. Apers

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  1. J. Ladriere
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  2. V. Senterre
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  3. D. Apers
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Ladriere, J., Senterre, V. & Apers, D. Mössbauer study on the gamma radiolysis of anhydrous cesium tris (oxalato) ferrate(III). Hyperfine Interact 70, 917–920 (1992). https://doi.org/10.1007/BF02397477

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  • DOI: https://doi.org/10.1007/BF02397477

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