Hyperfine Interactions

, Volume 55, Issue 1–4, pp 1145–1150 | Cite as

Comparison of characteristic temperatures determined by Mössbauer spectroscopy and X-ray diffraction

  • T. Nakazawa
  • H. Inoue
  • T. Shirai
Lattice Dynamics Phase Transitions

Abstract

Characteristic temperatures have been determined by both Mössbauer spectroscopy and X-ray diffraction for Prussian blue analogs of the type Fe[M(CN)6] (M=Co, Rh and Ir). For each Fe3+ in these compounds, the characteristic temperatures obtained from the Mössbauer parameters agree in tendency with those from the X-ray powder diffraction data. The values of the former are lower than those of the latter. This difference is thought to be caused by the different nature of the observed objects interacting with the electromagnetic waves, i.e. γ-ray and X-ray.

Keywords

Spectroscopy Thin Film Electromagnetic Wave Powder Diffraction Diffraction Data 

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References

  1. [1]
    G.K. Wertheim, D.N.E. Buchanan and H.J. Guggenheim, Phys. Rev. 2 (1970) 1392.CrossRefADSGoogle Scholar
  2. [2]
    J.W. Niemantsverdriet C.F.J. Flipse, B. Selman, J.J. Van Loef and A.M. Van Der Kraan, Phys. Lett. 100A (1984) 445.ADSGoogle Scholar
  3. [3]
    T.M. Sabine, Aust. J. Phys. 41 (1988) 413.ADSGoogle Scholar
  4. [4]
    F. Izumi, J. Crystallogr. Soc. Jpn. 27 (1985) 23.Google Scholar
  5. [5]
    H. Inoue, E. Fluck and S. Yanagisawa, Z. Naturforsch. 31b (1976) 167.Google Scholar
  6. [6]
    T. Komatsu and N. Soga, J. Appl. Phys. 51 (1981) 5926.CrossRefADSGoogle Scholar
  7. [7]
    T. Nakazawa, H. Inoue and T. Shirai, to be published.Google Scholar
  8. [8]
    R.R. Ryan and B.I. Swanson, Inorg. Chem. 12 (1974) 1681;CrossRefGoogle Scholar
  9. [8]a
    R.R. Ryan and B.I. Swanson, Inorg. Chem. 12 (1973) 283.CrossRefGoogle Scholar
  10. [9]
    A. Ludi, H.U. Güdel and M. Rüegg, Inorg. Chem. 9 (1970) 2224.CrossRefGoogle Scholar
  11. [10]
    N.A. Curry and W.A. Runciman, Acta Cryst. 12 (1956) 674.CrossRefGoogle Scholar
  12. [11]
    L.H. Jones, J. Chem. Phys. 41 (1964) 856.CrossRefGoogle Scholar
  13. [12]
    M. Sano, Y. Hatano, H. Kashiwagi and H. Yamatera, Bull. Chem. Soc. Jpn. 54 (1981) 1523.Google Scholar

Copyright information

© J.C. Baltzer A.G. Scientific Publishing Company 1990

Authors and Affiliations

  • T. Nakazawa
    • 1
  • H. Inoue
    • 1
  • T. Shirai
    • 1
  1. 1.Department of Applied ChemistryKeio UniversityYokohamaJapan

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