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The rapid formation of tin oxide pillared laponite by microwave heating: Characterisation by tin-119 Mössbauer spectroscopy, X-ray photoelectron spectroscopy and nuclear magnetic resonance

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Abstract

The intercalation of organotin-compounds into laponite and the formation of tin(IV) oxide pillars is rapidly achieved when performed in a microwave oven.119Sn Mössbauer- and x-ray- photoelectron-spectroscopy suggest that Ph3SnCl and Ph2SnCl2 undergo hydrolysis on the surface once sorbed. The treatment of Ph3SnCl/laponite with microwave radiation also induces the formation of a metallic phase which contains both tin and magnesium.

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Authors and Affiliations

  1. School of Chemistry, University of Birmingham, Edgbaston, B15 2TT, Birmingham, UK

    Frank J. Berry

  2. Department of Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, B4 7ET, Birmingham, UK

    R. Claire Ashcroft, Martin S. Beevers, Stephen P. Bond, Andrew Gelders, Monique A. M. Lawrence & William R. McWhinnie

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  1. Frank J. Berry
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  2. R. Claire Ashcroft
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  3. Martin S. Beevers
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  4. Stephen P. Bond
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  5. Andrew Gelders
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  6. Monique A. M. Lawrence
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  7. William R. McWhinnie
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Berry, F.J., Ashcroft, R.C., Beevers, M.S. et al. The rapid formation of tin oxide pillared laponite by microwave heating: Characterisation by tin-119 Mössbauer spectroscopy, X-ray photoelectron spectroscopy and nuclear magnetic resonance. Hyperfine Interact 68, 261–264 (1992). https://doi.org/10.1007/BF02396486

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