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Hyperfine Interactions

, Volume 68, Issue 1–4, pp 261–264 | Cite as

The rapid formation of tin oxide pillared laponite by microwave heating: Characterisation by tin-119 Mössbauer spectroscopy, X-ray photoelectron spectroscopy and nuclear magnetic resonance

  • Frank J. Berry
  • R. Claire Ashcroft
  • Martin S. Beevers
  • Stephen P. Bond
  • Andrew Gelders
  • Monique A. M. Lawrence
  • William R. McWhinnie
Chemical Structure and Bonding

Abstract

The intercalation of organotin-compounds into laponite and the formation of tin(IV) oxide pillars is rapidly achieved when performed in a microwave oven.119Sn Mössbauer- and x-ray- photoelectron-spectroscopy suggest that Ph3SnCl and Ph2SnCl2 undergo hydrolysis on the surface once sorbed. The treatment of Ph3SnCl/laponite with microwave radiation also induces the formation of a metallic phase which contains both tin and magnesium.

Keywords

Oxide Radiation Spectroscopy Hydrolysis Thin Film 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© J.C. Baltzer A.G., Scientific Publishing Company 1991

Authors and Affiliations

  • Frank J. Berry
    • 1
  • R. Claire Ashcroft
    • 2
  • Martin S. Beevers
    • 2
  • Stephen P. Bond
    • 2
  • Andrew Gelders
    • 2
  • Monique A. M. Lawrence
    • 2
  • William R. McWhinnie
    • 2
  1. 1.School of ChemistryUniversity of BirminghamBirminghamUK
  2. 2.Department of Chemical Engineering and Applied ChemistryAston UniversityBirminghamUK

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