Skip to main content
SpringerLink
Log in

Exchange interaction in trinuclear transition-metal complexes

  • Chemical Structure and Bonding
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Heterotrinuclear transition-metal complexes are of interest for the study of long-range magnetic interactions and as model compounds for the investigation of biological electron transport chains. The systems under study here contain paramagnetic Fe111-containing terminal units and a bridging unit with M11=Zn, Cu, Ni, Co, Fe, Mn. The spectroscopic methods applied include Mössbauer, — EPR- and magnetic susceptibility investigations. The spin-Hamiltonian analysis of the measured results yields information about the intramolecular super-exchange interactions among the various magnetic transmition-metal sites. In view of the 7Å separation between the two terminal Fe111 sites, the Fe111...Fe111 exchange coupling of the order −10cm−1 is large.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. L. Antolini, A.C. Fabretti, D. Catteschi, A. Giushi and R. Sessoli, Inorg. Chem. 29 (1990) 143, and references therein.

    Article  Google Scholar 

  2. O. Kahn, Structure and Bonding (Berlin), 68 (1987) 89, and references therein.

    Google Scholar 

  3. Ph. Chaudhuri, M. Winter, P. Fleischhauer, W. Haase, U. Flörke and H.-J. Haupt, J. Chem. Soc., Chem. Communications 23 (1990) 1728.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institut für Physik, Medizinische Universität, D-2400, Lübeck, Germany

    E. Bill, Ch. Butzlaff, A. X. Trautwein & H. Winkler

  2. Anorganische Chemie, Ruhr Universität, D-4630, Bochum, Germany

    M. Winter & Ph. Chaudhuri

Authors
  1. E. Bill
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Ch. Butzlaff
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. X. Trautwein
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. H. Winkler
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. M. Winter
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Ph. Chaudhuri
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Bill, E., Butzlaff, C., Trautwein, A.X. et al. Exchange interaction in trinuclear transition-metal complexes. Hyperfine Interact 68, 229–232 (1992). https://doi.org/10.1007/BF02396478

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02396478

Keywords

Search

Navigation