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121Sb Mössbauer spectroscopic study of a series of organoantimony(III) compounds

  • Chemical Structure and Bonding
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Abstract

A systematic study of organoantimony(III) compounds, SbR3, was attempted in view of the effect on Mössbauer parameters of the substituent on the aromatic ring. The Mössbauer parameters obtained in frozen organic solutions reflected the electronic effect caused by the characteristics of the substituents, electron donative or attractive, at the para position on the aromatic ring.

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References

  1. G.T. Morgan and F.M.G. Micklethwait, J. Chem. Soc. 99 (1911) 2286.

    Google Scholar 

  2. R.F. de Ketelaere, F.T. Delbeke and G.P. van der Kelen, J. Organomet. Chem. 30 (1971) 365.

    Article  Google Scholar 

  3. T. Takano, Y. Ito and M. Takeda, Radioisotopes 29 (1980) 341.

    Google Scholar 

  4. M. Takahashi, R. Oyama and M. Takeda, The 31st Symp. on Radiochemistry, Fukuoka, Japan (1987).

  5. L.H. Bowen, private communication (1984).

  6. G.K. Shenoy and J.M. Friedt, Phys. Rev. Lett. 31 (1973) 419.

    Article  ADS  Google Scholar 

  7. G.K. Shenoy and J.M. Friedt, Nucl. Instr. Meth. 116 (1974) 573.

    Article  Google Scholar 

  8. G.K. Shenoy, J.M. Freidt, H. Maletta and S.L. Ruby, in: Mössbauer Effect Methodology, ed. I.J. Gruverman, C.W. Seidel and K. Dieterly, Vol. 9 (Plenum Press, New York, 1974), p. 227.

    Google Scholar 

  9. see for example, S.H. Pine, J.B. Hendrickson, D.J. Cram and G.S. Hammond, Organic Chemistry, 4th ed. (McGraw Hill, Tokyo, 1981), Chap. 13.

    Google Scholar 

  10. H. Inoue, T. Nakagome, T. Kuroiwa, T. Shirai and E. Fluck, Z. Naturforsch. 42b (1987) 573.

    Google Scholar 

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Yanaga, M., Nakahara, H., Endo, K. et al. 121Sb Mössbauer spectroscopic study of a series of organoantimony(III) compounds. Hyperfine Interact 68, 197–200 (1992). https://doi.org/10.1007/BF02396470

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