Skip to main content
SpringerLink
Log in

Mössbauer parameters of a highly anisotropic low-spin ferric compound: Bis[tris(N-methylimidazol-2-yl) hydroxymethane] ferrate (III) tetrafluoroborate

  • Magnetism and Magnetic Materials
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

We have analyzed the Mössbauer spectra of a highly anisotropic low-spin ferric compound, [Fe(TICOH)2](BF4)3, taken in frozen solution as a function of temperature and field. Unlike other low-spin ferric compounds, [Fe(TICOH)2](BF4)3 shows a sharp six-line pattern with an overall s;litting of 14.2 mm/s in an applied field at 4.2 K. Good simulations are obtained using the model of Oosterhuis and Lang with a crystal field of axial symmetry. At higher temperature spin fluctuations become important, and a dynamic lineshape model with temperature- and field-dependent relaxation rates is used to simulate the data.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. N.N. Greenwood, and T.C. Gibb,Mössbauer Spectroscopy, (Chapman & Hall, 1971).

  2. W.T. Oosterhuis and G. Lang, Phys. Rev. 178 (1969) 439–456.

    Article  ADS  Google Scholar 

  3. J.S. Griffith, Nature, Lond. 180 (1957) 30–31.

    Google Scholar 

  4. S.M. Gorun, Ph.D. Thesis, 1986, MIT, unpublished.

  5. F.-J. Wu and D.M. Kurtz, Jr., J. Am. Chem. Soc. 111 (1989).

  6. F.-J. Wu and D.M. Kurtz, (unpublished).

  7. M.J. Clauser and M. Blume, Phys. Rev. B3 (1971) 583–591.

    Article  ADS  Google Scholar 

  8. C.P.S. Taylor, Biochim. Biophys. Acta 491 (1977) 137–149.

    Google Scholar 

  9. G.K. Shenoy and B.D. Dunlap, Phys. Rev. B13 (1976) 3709–3714.

    Article  ADS  Google Scholar 

  10. F. Gonzales-Jimenez, P. Imbert and F. Hartmann-Boutron, Phys. Rev. B9 (1974) 95–107.

    Article  ADS  Google Scholar 

  11. J.S. Griffith, Mol. Phys. 21 (1971) 135–139.

    ADS  MathSciNet  Google Scholar 

Download references

Author information

Author notes

  1. Kyung Seon Baek

    Present address: Physics Department, Yonsei University, Seoul, Korea

Authors and Affiliations

  1. Physics Department, University of Illinois at Urbana-Champaign, 61801, Urbana, IL, USA

    Kyung Seon Baek, P. G. Debrunner & Yao-Min Xia

  2. Chemistry Department, University of Georgia, 30602, Athens, GA, USA

    Feng-Jung Wu & D. M. Kurtz Jr.

Authors
  1. Kyung Seon Baek
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. G. Debrunner
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yao-Min Xia
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Feng-Jung Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. M. Kurtz Jr.
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baek, K.S., Debrunner, P.G., Xia, YM. et al. Mössbauer parameters of a highly anisotropic low-spin ferric compound: Bis[tris(N-methylimidazol-2-yl) hydroxymethane] ferrate (III) tetrafluoroborate. Hyperfine Interact 54, 447–451 (1990). https://doi.org/10.1007/BF02396070

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02396070

Keywords

Search

Navigation