Skip to main content
SpringerLink
Log in

Phase characterization in the Fe−Co−V and Fe−Co−Nb systems

  • Metals and Alloys
  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

Two distinct phases of the Fe−Co−Nb and three of the Fe−Co−V systems have been studied by means of X-ray diffraction and Mössbauer spectroscopy. The dependence of the lattice parameter of the alpha phase on the nominal solute content in equiatomic FeCo together with the alterations of the Mössbauer spectra have shown a very limited solubility of niobium in alpha FeCo. There are indications that the solubility of vanadium in alpha FeCo increases with increasing nominal content of solute in the alloy. A mechanism involving the withdrawal of cobalt from the alpha matrix to form a phase rich in Co and V (gamma) is proposed to explain such a varying solubility. The vanadium content of the sigma phase in equiatomic FeCo alloys with 22 wt% V is proposed to be less than 50 at%.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. D.W. Clegg, PhD thesis, University of Sheffield, 1973.

  2. M.W. Branson, R.V. Major, C.D. Pitt and R.D. Rawlings, J. Magn. Mag. Mat. 19 (1980) 22.

    Article  Google Scholar 

  3. K. Kawahara J. Mat. Sci. 18 (1983) 3437.

    Article  Google Scholar 

  4. A.I.C. Persiano and R.D. Rawlings, ASM J. Mat. Eng. 12 (1990) 21.

    Google Scholar 

  5. M. Oron, S. Strikman and J.D. Treves, J. Mat. Sci. 4 (1969) 581.

    Article  Google Scholar 

  6. A.I.C. Persiano and R.D. Rawlings, Phys. Stat. Sol. (a) 103 (1987) 547.

    Google Scholar 

  7. B. de Mayo, Phys. Rev. B 24 (11) (1981) 6503.

    Article  ADS  Google Scholar 

  8. G.V. Raynor and V.G. Rivlin, Intl. Met Rev. 28 (4) (1983) 211.

    Google Scholar 

  9. A.I.C. Persiano, PhD thesis, University of London, 1986.

  10. A.I.C. Persiano and R.D. Rawlings, Proc. 5th. RISO Intl. Symp. Metal. Mat. Sci. (1984) 411.

  11. M.F.S. Rezende, J.D. Ardisson, H.-D. Pfannes and A.I.C. Persiano, to be published.

  12. G.K. Wertheim, V. Jaccarino, J.H. Wernick and D.N.E. Buchanan, Phys. Rev. Lett. 12 (1964) 24.

    Article  ADS  Google Scholar 

  13. Y. Sumitomo, T. Moriya, H. Ino and F.E. Fujita, J. Phys. Soc. Japan 35 (1973) 461.

    Article  ADS  Google Scholar 

  14. E.S. Machlin and P.T. Gee, J. Solid State Chem. 24 (1978) 277.

    Article  ADS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Departamento de Fisica-UFMG, C.P. 702, 30161, Belo Horizonte, MG, Brazil

    M. F. S. Rezende, R. A. Mansur, H. -D. Pfannes & A. I. C. Persiano

Authors
  1. M. F. S. Rezende
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. R. A. Mansur
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. -D. Pfannes
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. I. C. Persiano
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Rezende, M.F.S., Mansur, R.A., Pfannes, H.D. et al. Phase characterization in the Fe−Co−V and Fe−Co−Nb systems. Hyperfine Interact 66, 319–323 (1991). https://doi.org/10.1007/BF02395880

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02395880

Keywords

Search

Navigation