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Goldanskii-Karyagin effect in α-SnF2: A neutron diffraction and Mössbauer absorption study

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Abstract

Single crystal neutron diffraction data have been obtained at several temperatures for α-SnF2. These data were used to evaluate the Goldanskii-Karyagin effect expected for the119Sn transition, and compared with the effect measured directly by means of the Mössbauer absorption in powdered samples, free of preferential orientation. These results provide further support for Karyagin's theory. The values of the anisotropy parameterg 11 obtained from the neutron diffraction data are somewhat lower than those obtained from the Mössbauer absorption.

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References

  1. V.I. Goldanskii, G.M. Gorodinskii, S.V. Karyagin, L.A. Korytho, L.M. Krizhanskii, E.F. Makarov, I.P. Suzdalev and V.V. Khrapov, Doklady Akad. Nauk SSSR 147(1962)127.

    Google Scholar 

  2. S.V. Karyagin, Doklady Akad. Nauk SSSR 148(1963)1102; Fiz. Tverd. Tela 8(1966)1733; 9(1967)2514; Solid State (Sov. Phys.) 8(1966)1397.

    Google Scholar 

  3. T.C. Gibb, R. Greatrex and N.N. Greenwood, J. Chem. Soc. (A) (1968)890.

  4. V.I. Goldanskii, E.F. Makarov and V.V. Khrapov, Phys. Lett. 3(1963)344; V.S. Shpinel, A.Yu. Aleksandrov, G.K. Ryasnin and O.Yu. Okhlobystin, Sov. Phys. JETP 21 (1965)47; H.A. Stöckler and H. Sano, Phys. Lett. 22A(1967)550; V.I. Goldanskii, E.F. Makarov, I.P. Suzdalev and I.A. Vinogradov, Phys. Rev. Lett. 20(1968) 137; R.M. Housley, U. Gonser and R. Grant, Phys. Rev. Lett. 20(1968)1273.

    Article  ADS  Google Scholar 

  5. R.H. Herber and S. Chandra, J. Chem. Phys. 52(1970)6045.

    Article  ADS  Google Scholar 

  6. R.C. McDonald, H. Ho-Kuen Hau and K. Eriks, Inorg. Chem. 15(1976)762.

    Article  Google Scholar 

  7. G. Dénès, J. Pannetier, J. Lucas and J.Y. Le Marouille, J. Solid State Chem. 30 (1979)335.

    Article  ADS  Google Scholar 

  8. T. Bircħall, G. Dénès, K. Ruebenbauer and J. Pannetier, J. Chem. Soc., Dalton Trans. (1981) 2296.

  9. W. Kündig, Nucl. Instr. Meth. 48(1967)219.

    Article  Google Scholar 

  10. K. Ruebenbauer and T. Birchall, Hyp. Int. 7(1979)125.

    Article  ADS  Google Scholar 

  11. K. Ruebenbauer and B. Sepioł, Hyp. Int. 23(1985)351.

    Article  ADS  Google Scholar 

  12. K. Ruebenbauer, Mössbauer spectroscopy, Advances in Colloid and Interface Science 23 (1985)257.

    Article  Google Scholar 

  13. M. Atac, B. Chrisman, P. Debrunner and H. Frauenfelder, Phys. Rev. Lett., 20(1968) 631.

    Article  ADS  Google Scholar 

  14. T.E. Cranshaw, J. Phys. E 7(1974)122.

    Article  ADS  Google Scholar 

  15. G.K. Shenoy, J.M. Friedt, H. Maletta and S.L. Ruby, Mössbauer Effect Meth. 9(1974) 277.

    Google Scholar 

  16. K.S. Singwi and A. Sjölander, Phys. Rev. 120(1960)1092.

    Article  ADS  Google Scholar 

  17. T. Birchall, G. Dénès, K. Ruebenbauer and J. Pannetier, J. Chem. Soc., Dalton Trans. (1981) 1831.

  18. M. Durand-Le Floch, U. Haeberlen and C. Müller, J. Physique 43 (1982)107.

    Google Scholar 

  19. G. Will and M.O. Bargouth, Z. Kristall. 153(1980)89.

    Article  Google Scholar 

  20. G. Dénès, J. Solid State Chem. 36(1981)20.

    Article  ADS  Google Scholar 

  21. J. Pannetier, G. Dénès, M. Durand and J.L. Buevoz, J. Physique, 41(1980)1019.

    Google Scholar 

  22. G. Dénès, J. Pannetier and J. Lucas, J. Solid State Chem. 33(1980)1.

    Article  ADS  Google Scholar 

  23. G. Heger, W.F. Kuhs and S. Massing, Rev. Phys. Appl. 19(1984)735.

    Google Scholar 

  24. M.S. Lehmann and F.K. Larsen, Acta Cryst. A30(1974)580.

    Article  Google Scholar 

  25. U.H. Zucker, E. Perenthaler, W.F. Kuhs, R. Bachmann and H. Schulz, J. Appl. Cryst. 16 (1983)538.

    Article  Google Scholar 

  26. R. Kmieć, K. Łatka and K. Ruebenbauer, Phys. Stat. Sol. B79(1977)K137.

    ADS  Google Scholar 

  27. M. Merisalo and J. Kuritta, J. Appl. Cryst. 11(1978)179.

    Article  Google Scholar 

  28. E. Acker, S. Haussühl and K. Recker, J. Crystal Growth 13/14(1972)467.

    Article  ADS  Google Scholar 

  29. L.A. Finger, University of Minnesota, Computer Program BADTEA (1965), revised in (1967).

  30. T.C. Gibb, B.A. Goodman and N.N. Greenwood, Chem. Commun. (1970)774.

  31. G. Dénès, Thèse d'Etat, Rennes, France (1978).

  32. J. Galy, G. Meunier, S. Anderson and A. Aström, J. Solid State Chem. 13(1975) 142.

    Article  ADS  Google Scholar 

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Author notes

  1. G. Dénes

    Present address: Department of Chemistry, Concordia University, 1455 de Maisonneuve Blvd. W., H3G 1M8, Montreal, Quebec, Canada

Authors and Affiliations

  1. Department of Chemistry and Institute for Materials Research, McMaster University, L8S 4M1, Hamilton, Ontario, Canada

    T. Birchall & G. Dénes

  2. Institute of Nuclear Physics, ul. Radzikowskiego 152, PL-31-342, Cracow, Poland

    K. Ruebenbauer

  3. Institut Laue-Langevin, B.P. No. 156X, F-38042, Grenoble, France

    J. Pannetier

Authors
  1. T. Birchall
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  2. G. Dénes
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  3. K. Ruebenbauer
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  4. J. Pannetier
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Birchall, T., Dénes, G., Ruebenbauer, K. et al. Goldanskii-Karyagin effect in α-SnF2: A neutron diffraction and Mössbauer absorption study. Hyperfine Interact 30, 167–183 (1986). https://doi.org/10.1007/BF02394316

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  • DOI: https://doi.org/10.1007/BF02394316

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