Skip to main content
SpringerLink
Log in

Rate of copper extraction and structure of model β-diketones and 4-acyl-5-pyrazolones

  • Solvent Extraction, Liquid Membranes, and Micellar Separations
  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The rate of copper extraction with individual 4-acyl-5-pyrazolones and the stability of various enolic and keto forms and their monohydrates were studied. The rate of extraction depends mainly upon the structure of substituent at position 4 and falls when the substituent becomes spacy. The effect of the substituent at position 1 is rather low. The enolic form with intramolecular hydrogen bonding is the most stable. It can form hydrates with water molecules without intramolecular hydrogen bond breaking.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. Szymanowski, Hydroxyoximes and Copper Hydrometallurgy, CRC Press, Boca Raton, USA, 1993.

    Google Scholar 

  2. M. Cox, D. Flett, Chem. Ind. 16 (1987).

  3. W. Mickler, E. Ehlemann, R. Herzschuh, B. Wenclawiak, L. Plaggenborg, Sep. Sci. Technol. 27 (1992) 1171.

    CAS  Google Scholar 

  4. W. Mickler, E. Uhlemann, R. Herzschuh, J. Prakt. Chem., 334 (1992) 435.

    Article  CAS  Google Scholar 

  5. B. S. Jensen, Acta Chem. Scand., 13 (1959) 1668.

    CAS  Google Scholar 

  6. W. Mickler, E. Uhlemann, Sep. Sci. Technol. 27 (1992) 1663.

    Google Scholar 

  7. W. Mickler, E. Uhlemann, Sep. Sci. Technol., 28 (1993) 1913.

    CAS  Google Scholar 

  8. W. Mickler, E. Uhlemann, Sep. Sci. Technol. 28 (1993) 2693.

    Google Scholar 

  9. K. Prochaska, R. Cierpiszewski, J. Szymanowski, E. Uhlemann, W. Mickler, Solvent Extr. Ion Exch., 13 (1993) 215.

    Google Scholar 

  10. J. J. P. Stewart, MOPAC v. 5.0, QCPE 455, University of Indiana, Blomington, IN, USA.

  11. K. Prochaska, M. Łożyński, J. Szymanowski, E. Uhlemann, W. Mickler, Solvent Extr. Ion Exch., 14 (1996) 491.

    CAS  Google Scholar 

  12. T. Kopczyński, M. Łożyński, K. Prochaska, A. Burdzy, R. Cierpiszewski, J. Szymanowski, Solvent. Extr. Ion Exch., 12 (1994) 701.

    Google Scholar 

  13. M. Bogacki, M. Łożyński, J. Szymanowski, Solvent Extr. Res. Dev. Japan, 1 (1994) 108.

    CAS  Google Scholar 

  14. M. Bogacki, J. Szymanowski, Solvent. Extr. Res. Dev. Japan, 2 (1995) 36.

    CAS  Google Scholar 

  15. D. Rusińska-Roszak, M. Łożyński, M. Korn, H.-G. Mack, J. Mol. Struct. (Theochem), 331 (1995) 95.

    Google Scholar 

  16. M. Bogacki, J. Szymanowski, Solvent. Extr. Res. Dev. Japan, 3 (1996) 10.

    CAS  Google Scholar 

  17. J. Szymanowski, C. Tondre, Solvent Extr. Ion Exch. 12 (1994) 873.

    CAS  Google Scholar 

  18. M. Majdan, R. P. Sperline, W. G. Gu, W.-H. Yu, H. Freiser, Solvent. Extr. Ion Exch., 7 (1987) 987.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Commodity, Academy of Economics, Al. Niepodłeglości 10, 60-967, Poznań, Poland

    R. Cierpiszewski

  2. Institute of Chemical Technology and Engineering, Poznań Technical University, Pl. Skłodowskiej-Curie 2, 60-965, Poznań, Poland

    D. Rusińska-Roszak, J. Szymanowski & E. Uhlemann

  3. Institut für Anorganische Chemie und Didaktik der Chemie, Universität Potsdam, Am Neuen Palais 10, D-14415, Potsdam, Germany

    W. Mickler

Authors
  1. R. Cierpiszewski
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. D. Rusińska-Roszak
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. J. Szymanowski
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. W. Mickler
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. E. Uhlemann
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Cierpiszewski, R., Rusińska-Roszak, D., Szymanowski, J. et al. Rate of copper extraction and structure of model β-diketones and 4-acyl-5-pyrazolones. J Radioanal Nucl Chem 228, 71–76 (1998). https://doi.org/10.1007/BF02387302

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF02387302

Keywords

Search

Navigation